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Substituent Effects in Radical Chemistry

  • Book
  • © 1986

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Editors:
  1. Heinz G. Viehe

    1. University of Louvain, Louvain-la-Neuve, Belgium

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  2. Zdenek Janousek

    1. University of Louvain, Louvain-la-Neuve, Belgium

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    You can also search for this editor in PubMed   Google Scholar

  3. Robert Merényi

    1. University of Louvain, Louvain-la-Neuve, Belgium

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Part of the book series: Nato Science Series C: (ASIC, volume 189)

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Table of contents (40 chapters)

  1. Front Matter

    Pages i-xiv
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  2. A Theoretical Approach to Substituent Effects in Radical Chemistry

    • G. Leroy, D. Peeters, M. Sana, C. Wilante
    Pages 1-48

  3. Sigma and PI Effects in Radicals

    • Timothy Clark
    Pages 49-68

  4. The Contrasting Strain Energies of Small Ring Carbon and Silicon Rings. The Relationship with free Radical Energies

    • Paul Ragué von Schleyer
    Pages 69-81

  5. Allylic and Allenic Capto-Dative Stabilization in Nitrogen Centered free Radicals

    • Daniel Kost, Morton Raban, Kalman Aviram
    Pages 83-86

  6. Conformational Preferences in ß-Substituted Ethyl Radicals: A Quantitative Analysis of Hyperconjugation, Homoconjugation, d-Orbital and Steric Effects.

    • Jacques Fossey
    Pages 87-90

  7. Substituent Effects on the Thermochemistry and Electrochemistry of Free Radicals

    • J. A. Hawari, J. M. Kanabus-Kaminska, D. D. M. Wayner, D. Griller
    Pages 91-105

  8. Some Applications of ESR Spectroscopy to the Study of Substituent Effects

    • G. W. Burton, L. J. Johnston, J. C. Walton, K. U. Ingold
    Pages 107-122

  9. Substituent Effects on Absolute Rate Constants and Arrhenius Parameters for the Addition of tert-Butyl Radicals to Alkenes

    • Hanns Fischer
    Pages 123-142

  10. Allylic Radicals—An ESR Spectroscopical Study

    • Reiner Sustmann
    Pages 143-166

  11. ESR-Spectroscopical Investigation of Capto-Dative Substituent Effects in Benzyl Radicals

    • H.-G. Korth, P. Lommes, R. Sustmann, L. Sylvander, L. Stella
    Pages 167-170

  12. The Effect of Substituents on Benzylic Radical Esr Hyperfine Coupling Constants. The σ α • Scale Based Upon Spin Delocalization.

    • Donald R. Arnold
    Pages 171-188

  13. Determination of Thermodynamic Stabilisation in Amino-Substituted Alkyl Radicals

    • Iain Maclnnes, John C. Walton, Derek C. Nonhebel
    Pages 189-190

  14. Phosphinylhydrazyls \({{R}_{2}}N\dot{N}P\left( 0 \right){{L}_{2}}.\) Influence of the Phosphinyl Group on the 3-Electron NN π Bond

    • P. Tordo
    Pages 191-194

  15. Substituent Effects on the Dimerization of Vinyl Nitroxides and on the Dissociation of Their Tricyclic Dimers

    • Hans Günter Aurich, Otto Bubenheim, Klaus-Dieter Mogendorf
    Pages 195-198

  16. Substituent Effects on the CC-Bond Strength.

    • H. Birkhofer, H. D. Beckhaus, C. Rüchardt
    Pages 199-218

  17. The Different Recombinations of Diphenyl Methyl Radicals Ph2 C.-R, R = tBu, CN, COOR’, COR’

    • W. P. Neumann, R. Stapel
    Pages 219-222

  18. Some Chemistry of Radical Ions

    • J. M. Tedder
    Pages 223-244

  19. Substituent Effects on the Methylenecyclopropane Rearrangement. A Probe for Free Radical Effects.

    • Xavier Creary
    Pages 245-262

  20. 2-Oxomorpholin-3-YL Radicals

    • Tad H. Koch
    Pages 263-270
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Keywords

Reviews

`This book as a top level scientific kaleidoscope is recommended to all organic chemists and related researchers who wish to know and apply the results of the modern radical chemistry. Anyone who would like to participate in the exciting further development of this area should read this book from cover to cover.'
Reaction Kinetics and Catalysis Letters, Vol. 34, No. 2, 1987

Editors and Affiliations

  • University of Louvain, Louvain-la-Neuve, Belgium

    Heinz G. Viehe, Zdenek Janousek, Robert Merényi

Bibliographic Information

  • Book Title: Substituent Effects in Radical Chemistry

  • Editors: Heinz G. Viehe, Zdenek Janousek, Robert Merényi

  • Series Title: Nato Science Series C:

  • DOI: https://doi.org/10.1007/978-94-009-4758-0

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: D. Reidel Publishing Company, Dordrecht, Holland 1986

  • Hardcover ISBN: 978-90-277-2340-6Published: 30 September 1986

  • Softcover ISBN: 978-94-010-8614-1Published: 26 September 2011

  • eBook ISBN: 978-94-009-4758-0Published: 06 December 2012

  • Series ISSN: 1389-2185

  • Edition Number: 1

  • Number of Pages: XIV, 482

  • Topics: Organic Chemistry

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