Highly Luminescent Lanthanide Complexes with Specific Coordination Structures
Authors: Miyata, Kohei
Free Preview- Nominated by Hokkaido University as an outstanding Ph.D. thesis
- Provides a general introduction to the principle of luminescence from lanthanide ions, lanthanide complexes, and coordination polymers
- Furnishes academic studies about specific coordination structures of lanthanide complexes with remarkable photophysical properties
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- About this book
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This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.
- Table of contents (7 chapters)
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General Introduction
Pages 1-13
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Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions
Pages 15-30
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Chameleon Luminophore for a Wide Range Temperature-Sensor Composed of Lanthanide Coordination Polymers
Pages 31-43
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Characteristic Structures and Photophysical Properties of Nona-Coordinated Eu(III) Complexes with Tridentate Phosphine Oxides
Pages 45-60
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Photophysical Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures
Pages 61-80
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Table of contents (7 chapters)
- Download Sample pages 2 PDF (744.3 KB)
- Download Table of contents PDF (116.8 KB)
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Bibliographic Information
- Bibliographic Information
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- Book Title
- Highly Luminescent Lanthanide Complexes with Specific Coordination Structures
- Authors
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- Kohei Miyata
- Series Title
- Springer Theses
- Copyright
- 2014
- Publisher
- Springer Japan
- Copyright Holder
- Springer Japan
- eBook ISBN
- 978-4-431-54944-4
- DOI
- 10.1007/978-4-431-54944-4
- Hardcover ISBN
- 978-4-431-54943-7
- Softcover ISBN
- 978-4-431-56398-3
- Series ISSN
- 2190-5053
- Edition Number
- 1
- Number of Pages
- XIII, 91
- Number of Illustrations
- 31 b/w illustrations, 21 illustrations in colour
- Topics
