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Highly Luminescent Lanthanide Complexes with Specific Coordination Structures

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  • © 2014
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Overview

Authors:
  1. Kohei Miyata

    1. ADEKA Corporation, Tokyo, Japan

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  • Nominated by Hokkaido University as an outstanding Ph.D. thesis
  • Provides a general introduction to the principle of luminescence from lanthanide ions, lanthanide complexes, and coordination polymers
  • Furnishes academic studies about specific coordination structures of lanthanide complexes with remarkable photophysical properties
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (7 chapters)

  1. Front Matter

    Pages i-xiii
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  2. General Introduction

    • Kohei Miyata
    Pages 1-13
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  3. Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions

    • Kohei Miyata
    Pages 15-30
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  4. Chameleon Luminophore for a Wide Range Temperature-Sensor Composed of Lanthanide Coordination Polymers

    • Kohei Miyata
    Pages 31-43
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  5. Characteristic Structures and Photophysical Properties of Nona-Coordinated Eu(III) Complexes with Tridentate Phosphine Oxides

    • Kohei Miyata
    Pages 45-60
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  6. Photophysical Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures

    • Kohei Miyata
    Pages 61-80
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  7. Solvent-Dependent Luminescence of Octa-Coordinated Eu(III) Complexes

    • Kohei Miyata
    Pages 81-88
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  8. Summary

    • Kohei Miyata
    Pages 89-90
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  9. Back Matter

    Pages 91-91
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Keywords

About this book

This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.

Authors and Affiliations

  • ADEKA Corporation, Tokyo, Japan

    Kohei Miyata

Bibliographic Information

  • Book Title: Highly Luminescent Lanthanide Complexes with Specific Coordination Structures

  • Authors: Kohei Miyata

  • Series Title: Springer Theses

  • DOI: https://doi.org/10.1007/978-4-431-54944-4

  • Publisher: Springer Tokyo

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: Springer Japan 2014

  • Hardcover ISBN: 978-4-431-54943-7Published: 17 April 2014

  • Softcover ISBN: 978-4-431-56398-3Published: 03 September 2016

  • eBook ISBN: 978-4-431-54944-4Published: 08 April 2014

  • Series ISSN: 2190-5053

  • Series E-ISSN: 2190-5061

  • Edition Number: 1

  • Number of Pages: XIII, 91

  • Number of Illustrations: 31 b/w illustrations, 21 illustrations in colour

  • Topics: Inorganic Chemistry, Optical and Electronic Materials, Physical Chemistry

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