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Structure of Liquids / Struktur der Flüssigkeiten

  • Book
  • © 1960

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Part of the book series: Handbuch der Physik Encyclopedia of Physics (HDBPHYS, volume 3 / 10)

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Table of contents (3 chapters)

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About this book

135 We first describe the thermodynamic theory of surface tension and adsorption, by the method of the dividing surface of GIBBS. The use of a dividing surface or its equivalent is indispensable for the treatment of a curved interface, as otherwise the concepts of the area and curvature of the interface, cannot be pre­ cisely defined. In the case of a plane interface, however, the concept of the dividing surface is not necessary and a valid alternative exposition has been proposed by GUGGEN­ HEIM [3J, [4J in treating the interface zone as a separate entity of some definite thickness bounded by two mathematical planes. We make, however, little mention of this method, since it seems to be of only minor importance in connec­ tion with the statistical treatment of an interface. To avoid any ambiguity, the treatment of a spherical interface given in this article is based not on the original method of GIBBS but on the method modified by HILL [8J and KONDO [9]. This method, however, is not applicable to non­ spherical interfaces, which will not be dealt with in this article. Although all the relations for a plane interface can be deduced from the cor­ responding ones for a spherical interface by putting the curvature equal to zero, the planar and the spherical cases are considered separately because of the prac­ tical importance and easy physical visualization of a plane interface.

Bibliographic Information

  • Book Title: Structure of Liquids / Struktur der Flüssigkeiten

  • Authors: H. S. Green, Syu Ono, Sohei Kondo, Frank P. Buff

  • Series Title: Handbuch der Physik Encyclopedia of Physics

  • DOI: https://doi.org/10.1007/978-3-642-45947-4

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag OHG. Berlin · Göttingen · Heidelberg 1960

  • Softcover ISBN: 978-3-642-45949-8Published: 25 February 2012

  • eBook ISBN: 978-3-642-45947-4Published: 06 December 2012

  • Series ISSN: 0085-140X

  • Series E-ISSN: 2197-4195

  • Edition Number: 1

  • Number of Pages: VI, 320

  • Topics: Physics, general

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