Skip to main content

Phase Transitions of Simple Systems

  • Book
  • © 2008

Overview

  • Describes the thermodynamics of ensembles of particles
  • Explains phase transition in gaseous and liquid systems
  • Both a reference book for researchers and a textbook for students
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Series on Atomic, Optical, and Plasma Physics (SSAOPP, volume 42)

This is a preview of subscription content, log in via an institution to check access.

Access this book

eBook USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Other ways to access

Licence this eBook for your library

Institutional subscriptions

Table of contents (14 chapters)

  1. Introduction

  2. Configurational Excitations and Aggregate States of Ensembles of Classical Particles

  3. Dynamics of Configurational Excitations in Ensembles of Classical Particles

Keywords

About this book

Thermodynamic concepts of aggregate states and their phase transitions - veloped during the 19th Century and are now the basis of our contem- rary understanding of these phenomena. Thermodynamics gives an universal, macroscopic description of the equilibrium properties of phase transitions - dependent of the detailed nature of the substances. However understanding the nature of phase transitions at the microscopic level requires a di?erent approach, one that takes into account the speci?cs of the interparticle int- actions. In this book, we lay the groundwork that connects the microscopic phenomena underlying phase changes with the macroscopic picture, but in a somewhat restricted way. We deal only with systems in which electronic excitations are not important, only with atomic systems, and only with - mogeneous systems. We also restrict our analysis to systems in which only pairwise interactions need be included, and, in many parts of the treatment, to systems in which one need consider only the interactions between nearest neighbor atoms. In establishing these restrictions, we can be guided by the solid and liquid states of inert gases and the phase transitions between them, althoughthesubsequentanalysisisrelevantandapplicableforaseriesofother physical systems. To study the behavior of a system of many interacting identical par- cles, we work extensively with its potential energy surface (PES), a surface in a many-dimensional space whose independent variables are the monomer coordinates or some transformation thereof. A central property of any m- tidimensional PES is its large number of local minima.

Authors and Affiliations

  • Department of Chemistry, University of Chicago^, Chicago, USA

    Stephen Berry

  • Institute of High Temperatures, Russian Academy of Sciences, Moscow, Russian Federation

    Boris Smirnov

About the authors

R. Stephen Berry is James Franck Distinguished Service Professor Emeritus in the Chemistry Department at The University of Chicago. He has studied phase changes and phase equilibria for twenty years. He is a MacArthur Fellow and a Member of the National Academy of Sciences of the U.S.A., and has been author or coauthor of five books prior to this. He and his coauthor of this book have known each other for over 40 years, from the time both were working on atomic collision processes. They have been collaborating for about 10 years, in their studies of clusters and of phase transitions.

Boris M. Smirnov is a distinguished physicist who worked for many years at the Institute for Ball Lightning, prior to his joining the Institute for High Temperatures in Moscow.

Bibliographic Information

Publish with us