Lecture Notes in Chemistry

One-Dimensional Organometallic Materials

An Analysis of Electronic Structure Effects

Authors: Böhm, Michael C.

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About this book

This lecture note gives an analysis of electronic structure effects for a new class of molecular solids, i. e. one-dimensional organometal­ lic systems formed by transition-met. l atoms that are embedded in a matrix of macrocyclic organic ligands. These systems as well as orga­ nic metals have focused considerable interest due to the potential formation of high-mobility charge carriers. For the present author it is difficult to participate in this restriction on a single physical property (i. e. high electronic conductivities, technical applications, etc. ). The lecture note is hopefully a small contribution to enhance the general understanding of certain electronic properties in organo­ metallic polymers. Those problems have been considered in the first place that seem to form a theoretical deficit in one specific field of solid-state chemistry. For the reader it will become evident that this contribution is a compromise always guided and limited by boundaries: i) An attempt to present problems to a ·chemical· audience which have their roots in solid-state physics. ii) The model calculations are limited by the currently available computational facilities. This ·boundary· implies that the compu­ tational data a~e subject to severe theoretical approximations. iii) Theorists have often a strong tendency to identify their numeri­ cal results and models with physical effects. Also this lecture note is not free of this almost universal trend. Nevertheless the author hopes that this text leads to some insight into a rather modern research field. M. e. B6hm I.

Table of contents (17 chapters)

Table of contents (17 chapters)

Buy this book

eBook $119.00
price for USA in USD (gross)
  • ISBN 978-3-642-93351-6
  • Digitally watermarked, DRM-free
  • Included format: PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $159.00
price for USA in USD
  • ISBN 978-3-540-17216-1
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
One-Dimensional Organometallic Materials
Book Subtitle
An Analysis of Electronic Structure Effects
Authors
Series Title
Lecture Notes in Chemistry
Series Volume
45
Copyright
1987
Publisher
Springer-Verlag Berlin Heidelberg
Copyright Holder
Springer-Verlag Berlin Heidelberg
eBook ISBN
978-3-642-93351-6
DOI
10.1007/978-3-642-93351-6
Softcover ISBN
978-3-540-17216-1
Series ISSN
0342-4901
Edition Number
1
Number of Pages
V, 181
Topics