Lecture Notes in Chemistry

Sulphone Molecular Structures

Conformation and Geometry from Electron Diffraction and Microwave Spectroscopy; Structural Variations

Authors: Hargittai, Istvan

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About this Textbook

Recently, the molecular structures of a relatively large number of sulphone compounds have been elucidated in the vapour phase by electron diffraction and microwave spectroscopy. The main purpose of these studies is the determination of the sulphur bond configuration and the conformational properties. This leads to the observation and correlation of characteristic structural variations as various ligands are attached to the S02 group and as comparisons are made with related molecules. Today it may be said that the structure of sulphone molecules is relatively well studied, and it appeared necessary to systematize the accumulated experimental data after critical considerations. This is done in the first part of this monograph. The second part presents the observed characteristic structural variations. Attempts are made to interpret these variations by valence shell electron pair repulsions and-non-bonded interactions. Correlation relationships between geometric and vibrational parameters are also presented. It is the metrical aspects of the molecular structure which are primarily considered. Since they correlate with other aspects of the molecular structure, e.g. electronic, it is hoped that the experimental information on the molecular geometry provides stim­ ulus for further experimental, and, in particular, theoretical work on sulphones and related systems. IV It is attempted to cover all electron diffraction and micro­ wave spectroscopic investigations on sulphone molecules to date. Admittedly, however, relatively larger weight is given to the electron diffraction studies originating from the author's own laboratory.

Table of contents (7 chapters)

Table of contents (7 chapters)

Buy this book

eBook $99.00
price for USA in USD (gross)
  • ISBN 978-3-642-93078-2
  • Digitally watermarked, DRM-free
  • Included format: PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $129.00
price for USA in USD
  • ISBN 978-3-540-08654-3
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
Sulphone Molecular Structures
Book Subtitle
Conformation and Geometry from Electron Diffraction and Microwave Spectroscopy; Structural Variations
Authors
Series Title
Lecture Notes in Chemistry
Series Volume
6
Copyright
1978
Publisher
Springer-Verlag Berlin Heidelberg
Copyright Holder
Springer-Verlag Berlin Heidelberg
eBook ISBN
978-3-642-93078-2
DOI
10.1007/978-3-642-93078-2
Softcover ISBN
978-3-540-08654-3
Series ISSN
0342-4901
Edition Number
1
Number of Pages
VIII, 176
Topics