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Ligated Transition Metal Clusters in Solid-state Chemistry

The legacy of Marcel Sergent

  • Book
  • © 2019

Overview

  • Presents a brief history of ligated transition metal clusters in solid-state chemistry
  • Provides a review of the recent developments in this field
  • Multi-authored volume with contributions from world renowned experts in the field

Part of the book series: Structure and Bonding (STRUCTURE, volume 180)

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Table of contents (6 chapters)

Keywords

About this book

This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few. 

 

Editors and Affiliations

  • Institut des Sciences Chimiques de Rennes – UMR 6226, Univ Rennes, CNRS, Rennes, France

    Jean-François Halet

About the editor

Jean-François Halet’s research centers on the understanding of the chemical bond in transition metal inorganic chemistry. He uses a variety of quantum chemical computational tools such as Extended Hückel, Ab initio and Density Functional methods to tackle problems of electron-counting, structure, physical properties and reactivity of both molecular and solid state systems. When possible, structural similarities between molecular and solid state compounds are analyzed. The main recent investigations of J.-F. Halet concern (i) The electronic structure of large (molecular, nanosized, and solid-state) inorganic transition metal clusters; (ii) The study of the metal-to-carbon bonding and physical properties in polymetallic compounds containing carbon ligands; (iii) The understanding of the structural arrangement and the physical properties, especially thermoellectrical properties, of solid-state compounds such as borides, boride carbides and nitrides.

Bibliographic Information

  • Book Title: Ligated Transition Metal Clusters in Solid-state Chemistry

  • Book Subtitle: The legacy of Marcel Sergent

  • Editors: Jean-François Halet

  • Series Title: Structure and Bonding

  • DOI: https://doi.org/10.1007/978-3-030-25124-6

  • Publisher: Springer Cham

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG 2019

  • Hardcover ISBN: 978-3-030-25123-9Published: 25 September 2019

  • Softcover ISBN: 978-3-030-25126-0Published: 25 September 2020

  • eBook ISBN: 978-3-030-25124-6Published: 29 August 2019

  • Series ISSN: 0081-5993

  • Series E-ISSN: 1616-8550

  • Edition Number: 1

  • Number of Pages: IX, 193

  • Number of Illustrations: 36 b/w illustrations, 73 illustrations in colour

  • Topics: Organometallic Chemistry, Inorganic Chemistry, Physical Chemistry, Spectroscopy/Spectrometry, Catalysis

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