Liquid-Phase Reaction Rate Constants

Authors: Denisov, E. T.

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About this book

The past 25 years in chemical kinetics have seen major advances in studyiqg the mechanisms of complex chemical re­ actions, in particular free radical reactions. Many differ­ ent methods have been developed for quantitative studies of elementary chemical reactions. Thousands of rate constants have been measured, for hundreds of diverse chemical reac­ tions. It is becoming more and more difficult for the chemist to orient himself in the voluminous and rapidly growing liter­ ature of chemical reaction kinetics. This leads to major expenditures of time in searching out, collecting. and eval­ uating quantitative kinetic data; to unnecessary repetition (duplication) of research; and to a situation in which the rich material already accumulated in the field of chemical kinetics is very often not fully utilized in comparing, interpreting, and analyzing new experimental data. There is a pressing need for the creation of a series of handbooks on reaction rate constants. Such work was begun several years ago at the initiative of V. N. Kondrat'ev, and is now going forward under his direction at the Institute of Chemical Physics of the USSR Academy of Sciences. This book is devoted to liquid-phase, homolytic reactions. Part One contains data on monomolecular reactions in which molecules decompose to form radicals, as well as data on bi­ molecular and trimolecular reactions that form free radicals.

Table of contents (13 chapters)

  • Monomolecular Reactions

    Denisov, E. T.

    Pages 3-85

  • Bimolecular and Trimolecular Reactions

    Denisov, E. T.

    Pages 87-108

  • The Cage Effect

    Denisov, E. T.

    Pages 109-134

  • Methods for Measuring Rate Constants of Radical Reactions

    Denisov, E. T.

    Pages 157-172

  • Isomerization and Decomposition of Free Radicals

    Denisov, E. T.

    Pages 173-177

Buy this book

eBook $84.99
price for USA in USD (gross)
  • ISBN 978-1-4684-8300-0
  • Digitally watermarked, DRM-free
  • Included format: PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $109.00
price for USA in USD
  • ISBN 978-1-4684-8302-4
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
Liquid-Phase Reaction Rate Constants
Authors
Copyright
1974
Publisher
Springer US
Copyright Holder
IFI/Plenum Data Company
eBook ISBN
978-1-4684-8300-0
DOI
10.1007/978-1-4684-8300-0
Softcover ISBN
978-1-4684-8302-4
Edition Number
1
Number of Pages
XXVI, 772
Topics