The Chemistry of Nitrate Radical (NO3) and Dinitrogen Pentoxide (N2O5) in Beijing

1. Front Matter

   Pages i-xiv

   PDF

2. Introduction

   • Haichao Wang

   Pages 1-24

3. Instrumentation

   • Haichao Wang

   Pages 25-44

4. Field Measurements

   • Haichao Wang

   Pages 45-64

5. NO3 Reactivity and N2O5 Uptake Coefficient

   • Haichao Wang

   Pages 65-94

6. Atmospheric Impacts

   • Haichao Wang

   Pages 95-112

7. Conclusions and Outlook

   • Haichao Wang

   Pages 113-116

This book systematically describes the instrument setup for the measurement of nitrate radical (NO₃) and dinitrogen pentoxide (N₂O₅), as well as the mixing ratio, chemical behaviors, and atmospheric impacts of NO₃ and N₂O₅ in Beijing, China. It also discusses the instrument design and data analysis method in detail. Based on several field measurements of NO₃ and N₂O₅ in Beijing, it shows the variation in concentration and the budget of NO₃ and N2O5. The N₂O₅ heterogeneous uptake coefficient was determined using various methods, and the relationship between the N₂O₅ uptake coefficient and the particle properties was demonstrated, as well as the impact of NO₃–N₂O₅ chemistry to the atmospheric oxidation and the formation of particulate nitrate. These results increase our understanding of nighttime chemistry and provide insights into the role of NO₃–N₂O₅ chemistry in other polluted regions.

• Nitrate radical
• Dinitrogen pentoxide
• Cavity enhanced absorption spectroscopy
• Field observation
• Atmospheric oxidation
• Heterogeneous hydrolysis
• Particulate nitrate formation
• air pollution and air quality

• State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China

  Haichao Wang

Dr. Haichao Wang received a Ph.D. in environmental science at Peking University (PKU) in 2018. Now he is an Associate Professor at Sun Yat-sen University. His research interests include the development of high sensitivity optical instrumentation for laboratory and field studies of atmospheric trace gases (e.g., NO₃, N₂O₅), and the chemical behaviors and impacts of reactive nitrogen species in the atmosphere. He has published more than 20 research papers in this area. He won the President Scholarship for Ph.D. Students of PKU in 2016-2018, and the Qian Yi Environment Award in 2017. His Ph.D. thesis was selected as the outstanding doctor degree dissertations in PKU in 2018, and he won the excellent post-doctor in PKU during 2018-2020.

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