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Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Metal Complex

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  • © 2021

Overview

Authors:
  1. Kenichi Endo

    1. Institute for Chemical Research, Kyoto University, Gokasho, Japan

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  • Nominated as an outstanding Ph.D. thesis by the University of Tokyo
  • Presents synthetic strategies for metal complexes in detail
  • Introduces unique techniques to distinguish similar complexes

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (4 chapters)

  1. Front Matter

    Pages i-xv
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  2. General Introduction

    • Kenichi Endo
    Pages 1-8

  3. Heterometallic CoIINi 3 II Complex

    • Kenichi Endo
    Pages 9-40

  4. Tetrahedral Chiral-at-Metal ZnII Complex

    • Kenichi Endo
    Pages 41-76

  5. Conclusions

    • Kenichi Endo
    Pages 77-78

  6. Back Matter

    Pages 79-80
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Keywords

About this book

This book describes novel synthetic methodologies for two kinds of structurally elaborate metal complexes: a heterometallic complex and a tetrahedral chiral-at-metal complex. The book provides the tools and inspiration to chemists for development of metal complexes with wide structural diversity than had previously been possible. For each of the two topics, existing synthetic methods for similar compounds are discussed first, and then new strategies are presented, followed by the demonstration of the synthesis of novel compounds supported by experimental results.


Both of the final products in this research, a Co–Ni heterometallic complex covered in the first topic and a tetrahedral chiral-at-metal complex in the second one are difficult to obtain by using common synthetic methods for thermodynamic reasons. This research achieved highly selective syntheses of these compounds using newly designed strategies that enable precise kinetic control. Suchan approach will be useful for synthesizing other new metal complexes.


Since the last century, organic chemistry has flourished with the development of a variety of synthetic techniques that make precise kinetic control possible. Coordination chemistry of 3d or main-group transition metals has been mainly based on simple one-step reactions that yield only thermodynamic products. The publication of this book helps pave the way to kinetically controlled precise syntheses of various metal complexes.




Authors and Affiliations

  • Institute for Chemical Research, Kyoto University, Gokasho, Japan

    Kenichi Endo

About the author

Kenichi Endo received his B.Sc., M.Sc., and Ph.D. in chemistry from the School of Science, The University of Tokyo in 2015, 2017, and 2020, respectively. He is now a postdoctoral researcher at Kyoto University. His research interests focus on synthesis of metal complexes with elaborate structures and catalytic activity of metal complexes.

Bibliographic Information

  • Book Title: Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Metal Complex

  • Authors: Kenichi Endo

  • Series Title: Springer Theses

  • DOI: https://doi.org/10.1007/978-981-16-1163-6

  • Publisher: Springer Singapore

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2021

  • Hardcover ISBN: 978-981-16-1162-9Published: 02 April 2021

  • Softcover ISBN: 978-981-16-1165-0Published: 02 April 2022

  • eBook ISBN: 978-981-16-1163-6Published: 01 April 2021

  • Series ISSN: 2190-5053

  • Series E-ISSN: 2190-5061

  • Edition Number: 1

  • Number of Pages: XV, 80

  • Number of Illustrations: 36 b/w illustrations, 28 illustrations in colour

  • Topics: Inorganic Chemistry, Organometallic Chemistry, Chemistry/Food Science, general

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