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Key Structural Factors of Group 5 Metal Oxide Clusters for Base Catalytic Application

  • Book
  • © 2020

Overview

Authors:
  1. Shun Hayashi

    1. The University of Tokyo, Tokyo, Japan

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  • Nominated as an outstanding Ph.D. thesis by the University of Tokyo
  • Describes in detail the experimental and theoretical evaluation of base catalysis
  • Provides rational design principles for base catalysts

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (6 chapters)

  1. Front Matter

    Pages i-xii
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  2. Introduction

    • Shun Hayashi
    Pages 1-24

  3. Brønsted Base Catalysis of [Nb10O28]6−

    • Shun Hayashi
    Pages 25-40

  4. Effect of Counter Cations on Base Catalysis of [Nb10O28]6−

    • Shun Hayashi
    Pages 41-53

  5. Effect of Local Structures on Lewis Base Catalysis of [Nb10O28]6−

    • Shun Hayashi
    Pages 55-67

  6. Effect of Constituent Metals on Base Catalysis of Hexametalate Clusters

    • Shun Hayashi
    Pages 69-84

  7. Concluding Remarks

    • Shun Hayashi
    Pages 85-90

  8. Back Matter

    Pages 91-92
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Keywords

About this book

This book provides detailed information on the base catalysis of group 5 (Nb, Ta) metal oxide clusters by elucidating how the structural factors such as constituent metals, counter cations, and local structures of base sites affect their catalysis. Uniquely, it reveals the effects of key structural factors at the molecular level by combining experimental and theoretical approaches. The findings presented here provide rational design principles for base catalysis and will foster the development of promising catalysts for solving current and future energy and environmental problems. 

Authors and Affiliations

  • The University of Tokyo, Tokyo, Japan

    Shun Hayashi

About the author

Shun Hayashi is a Postdoctoral Fellow at Tokyo Metropolitan University. His work mainly involves catalytic chemistry and cluster science. He received his Bachelor, Master and PhD in Science from the University of Tokyo in 2014, 2016 and 2019, respectively. He was awarded a research fellowship for young scientists from the Japan Society for the Promotion of Science (JSPS), and was supported by JSPS during his doctoral program.

Bibliographic Information

  • Book Title: Key Structural Factors of Group 5 Metal Oxide Clusters for Base Catalytic Application

  • Authors: Shun Hayashi

  • Series Title: Springer Theses

  • DOI: https://doi.org/10.1007/978-981-15-7348-4

  • Publisher: Springer Singapore

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: Springer Nature Singapore Pte Ltd. 2020

  • Hardcover ISBN: 978-981-15-7347-7Published: 09 August 2020

  • Softcover ISBN: 978-981-15-7350-7Published: 10 August 2021

  • eBook ISBN: 978-981-15-7348-4Published: 08 August 2020

  • Series ISSN: 2190-5053

  • Series E-ISSN: 2190-5061

  • Edition Number: 1

  • Number of Pages: XII, 92

  • Number of Illustrations: 53 b/w illustrations, 32 illustrations in colour

  • Topics: Nanochemistry, Catalysis, Physical Chemistry

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