Authors:
- The first and only book that comprehensively describes the opportunities quinoxalines offer as reagents for the synthesis of biologically important condensed derivatives
- The book explains new acid-catalyzed rearrangements of quinoxalinones giving benzimidazoles when exposed to nucleophilic reactants, thus leading to biheterocyclic systems
- The understanding of the methods and mechanisms of the reactions presented will allow synthetic chemists to extend these ideas to other processes in achieving their goals
- Includes supplementary material: sn.pub/extras
Buy it now
Buying options
Tax calculation will be finalised at checkout
Other ways to access
This is a preview of subscription content, log in via an institution to check for access.
Table of contents (6 chapters)
-
Front Matter
-
Back Matter
About this book
This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on “Condensed Pyrazines” by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.
Authors and Affiliations
-
Kazan Scientific Center, A.E. Arbuzov Inst. of Org. and Phy. Chem, Kazan, Russia
Vakhid A. Mamedov
About the author
Bibliographic Information
Book Title: Quinoxalines
Book Subtitle: Synthesis, Reactions, Mechanisms and Structure
Authors: Vakhid A. Mamedov
DOI: https://doi.org/10.1007/978-3-319-29773-6
Publisher: Springer Cham
eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)
Copyright Information: Springer International Publishing Switzerland 2016
Hardcover ISBN: 978-3-319-29771-2Published: 06 May 2016
Softcover ISBN: 978-3-319-80651-8Published: 27 May 2018
eBook ISBN: 978-3-319-29773-6Published: 26 April 2016
Edition Number: 1
Number of Pages: XV, 437
Number of Illustrations: 45 b/w illustrations, 546 illustrations in colour
Topics: Organic Chemistry, Medicinal Chemistry, Industrial Chemistry/Chemical Engineering