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Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties

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  • © 2020

Overview

Authors:
  1. Mingoo Jin

    1. Graduate School of Chemical Science and Engineering, Hokkaido University, Sapporo, Japan

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  • Nominated as an outstanding Ph.D. thesis by Hokkaido University
  • Facilitates learning with tutorials in the introduction, which contain ample background information
  • Explains the material design concept and external stimuli-responsive luminescence properties of crystalline materials

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (6 chapters)

  1. Front Matter

    Pages i-x
    Download chapter PDF

  2. General Introduction

    • Mingoo Jin
    Pages 1-15

  3. Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) Isocyanide Complex with Reactivation by Mechanical Grinding

    • Mingoo Jin
    Pages 17-81

  4. Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety

    • Mingoo Jin
    Pages 83-102

  5. Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions Between Chiral and Non-chiral Space Groups

    • Mingoo Jin
    Pages 103-126

  6. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color

    • Mingoo Jin
    Pages 127-156

  7. Thermo-Responsive Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of Phosphine-Gold(I) Complex

    • Mingoo Jin
    Pages 157-191
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Keywords

About this book

This book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. 


The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals’ chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence.   


The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies. 




Authors and Affiliations

  • Graduate School of Chemical Science and Engineering, Hokkaido University, Sapporo, Japan

    Mingoo Jin

About the author

Mingoo Jin is an Assistant Professor at Hokkaido University. He got a Ph.D. under the supervision of Professor Hajime Ito at Hokkaido University in 2018. His Ph.D. research subject was “Development of Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties”. After graduation he started as a postdoctoral researcher in Professor Miguel A. Garcia-Garibay's laboratory, University of California Los Angeles, and is investigating luminescent functional materials based on amphidynamic crystals. His research interests are Organometallic Chemistry, Coordination Chemistry, Polymer Chemistry, Computational Chemistry and Luminescent Solid-State Materials.

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