Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry

1. Front Matter

   Pages i-xii

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2. Introduction

   • Izabella Brand

   Pages 1-5

3. Polarization Modulation Infrared Reflection Absorption Spectroscopy: From Theory to Experiment

   • Izabella Brand

   Pages 7-45

4. In Situ PM IRRAS Studies of Redox-Inactive Molecular Films Adsorbed on Electrodes

   • Izabella Brand

   Pages 47-96

5. In Situ PM IRRAS Studies of Redox-Active Molecular Films Adsorbed on Electrode Surfaces

   • Izabella Brand

   Pages 97-115

6. Back Matter

   Pages 117-122

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This book describes the physical basis of polarization modulation infrared reflection-absorption spectroscopy and its application in electrochemical studies. It provides a concise yet comprehensive review of the research done in this field in the last 20 years. Electrochemical methods are used to determine the rate and mechanism of charge transfer reactions between an electrode and species adsorbed or diffusing to its surface. In the past two decades PM-IRRAS has grown to be one of the most important vibrational spectroscopy techniques applied to investigate structural changes taking place at the electrochemical interface. The monograph presents foundations of this technique and reviews in situ studies of redox-inactive and redox-active films adsorbed on electrode surfaces. It also discusses experimental conditions required in electrochemical and spectroscopic studies and presents practical solutions to perform efficient experiments. As such, it offers an invaluable resource for graduate and postgraduate students, as well as for all researchers in academic and industrial laboratories.

• spectroelectrochemistry
• infrared reflection-absorption spectroscopy
• external IR reflection
• IRRAS
• PM-IRRAS
• molecular film
• adsorption

• Department of Chemistry, University of Oldenburg, Oldenburg, Germany

  Izabella Brand

Izabella Brand is a Privatdozentin at the Carl von Ossietzky University of Oldenburg, Germany. She graduated in 1997 and obtained her PhD degree in chemistry in 2001 at the University of Warsaw, Poland. After graduation, she spent two years as a postdoctoral researcher at the University of Guelph, Canada. She then worked as research assistant at the Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland (2004-2005) and at the Carl von Ossietzky University of Oldenburg, Germany (2005-2014), where she habilitated in 2014. Dr. Brand is author and coauthor of almost 50 research papers, 2 book chapters and 1 book.

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