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Springer Theses

Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid–Solid Interface

Authors: Sawato, Tsukasa

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  • Nominated as an outstanding Ph.D. thesis by Tohoku University 
  • Highlights new chemical phenomena unique to liquid–solid interfaces 
  • Shares detailed information on various experimental operations and results for chemical reactions at liquid–solid interfaces 
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eBook 106,99 €
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  • ISBN 978-981-15-3192-7
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Hardcover 137,14 €
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About this book

In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid–solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid–solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid–solid interfaces not found in solutions. 
Detailed results are provided for new chemical reactions at liquid–solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid–solid interface. 

About the authors

Dr. Tsukasa Sawato is a Postdoctoral Fellow at Tohoku University. He works on helicene project, and he synthesized several helicene oligomers and examined stimulus responses with emphasis on surface interactions in solution. He received his Bachelor, Master and PhD in Pharmaceutical Sciences from Tohoku University in 2014, 2016 and 2019, respectively. He was awarded a research fellowship for young scientists from the Japan Society for the Promotion of Science (JSPS), and was supported by JSPS during his doctoral program.


Table of contents (7 chapters)

Table of contents (7 chapters)
  • Introduction

    Pages 1-6

    Sawato, Tsukasa

  • Synthesis and Homo-double-helix Formation of Oxymethylenehelicene Oligomers

    Pages 7-11

    Sawato, Tsukasa

  • Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid–Solid Interface

    Pages 13-24

    Sawato, Tsukasa

  • Mechanical Stirring Induces Hetero-double-helix Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution

    Pages 25-39

    Sawato, Tsukasa

  • Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers

    Pages 41-60

    Sawato, Dr. Tsukasa

Buy this book

eBook 106,99 €
price for France (gross)
  • ISBN 978-981-15-3192-7
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Hardcover 137,14 €
price for France (gross)
  • ISBN 978-981-15-3191-0
  • Free shipping for individuals worldwide
  • Immediate ebook access, if available*, with your print order
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid–Solid Interface
Authors
Series Title
Springer Theses
Copyright
2020
Publisher
Springer Singapore
Copyright Holder
Springer Nature Singapore Pte Ltd.
eBook ISBN
978-981-15-3192-7
DOI
10.1007/978-981-15-3192-7
Hardcover ISBN
978-981-15-3191-0
Series ISSN
2190-5053
Edition Number
1
Number of Pages
XII, 83
Number of Illustrations
8 b/w illustrations, 59 illustrations in colour
Topics

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