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  • © 2016

Underpotential Deposition

From Fundamentals and Theory to Applications at the Nanoscale

  • The first book on this topic covering the nanoscale
  • Provides a critical, comprehensive review of the relevant literature
  • Introduces cutting-edge modelling
  • Includes supplementary material: sn.pub/extras

Part of the book series: Monographs in Electrochemistry (MOEC)

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Table of contents (7 chapters)

  1. Front Matter

    Pages i-xii
  2. Introduction

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 1-15
  3. Experimental Techniques and Structure of the Underpotential Deposition Phase

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 17-89
  4. Phenomenology and Thermodynamics of Underpotential Deposition

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 91-161
  5. Applications of Underpotential Deposition on Bulk Electrodes as a Model System for Electrocatalysis

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 163-197
  6. Modelling of Underpotential Deposition on Bulk Electrodes

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 199-276
  7. Underpotential Deposition and Related Phenomena at the Nanoscale: Theory and Applications

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 277-334
  8. What Is Coming Next?

    • Oscar Alejandro Oviedo, Luis Reinaudi, Silvana Graciela García, Ezequiel Pedro Marcos Leiva
    Pages 335-348
  9. Back Matter

    Pages 349-361

About this book

With this volume, Ezequiel P. M. Leiva and co-authors fill a gap in the available literature, by providing a much-needed, comprehensive review of the relevant literature for electrochemists, materials scientists and energy researchers. For the first time, they present applications of underpotential deposition (UPD) on the nanoscale, such as nanoparticles and nanocavities, as well as for electrocatalysis. They also discuss real surface determinations and layer-by-layer growth of ultrathin films, as well as the very latest modeling approaches to UPD based on nanothermodynamics, statistical mechanics, molecular dynamics and Monte-Carlo simulations.

Reviews

“This book gives the reader the possibility to gain sufficiently deep insight into the upd phenomenon, both in its applied and theoretical aspects. It can be very useful for specialists in different fields of electrochemistry, surface science and physics, material science, and other fields of science; furthermore, it can serve as the most valuable and unique guidebook for those engaged in upd modeling by the methods of nanothermodynamics, statistical mechanics, molecular dynamics, and Monte Carlo simulations.” (O. A. Petrii, Journal of Solid State Electrochemistry, Vol. 20, 2016)

Authors and Affiliations

  • Departamento de Matemática y Física, Facultad de Ciencias Químicas, INFIQC, Universidad Nacional de Córdoba, Córdoba, Argentina

    Oscar Alejandro Oviedo, Luis Reinaudi, Ezequiel Pedro Marcos Leiva

  • Departamento de Ingeniería Química, Universidad Nacional del Sur, Bahía Blanca, Argentina

    Silvana Garcia

About the authors

Oscar A. Oviedo is Assistant Professor in Physico-Chemical Research Institute of Córdoba (INFIQC-CONICET) at the University of Córdoba, Argentina. His research areas are theoretical electrochemistry, electrocatalysis and in computer developments in physical chemistry.
Luis Reinaudi works as a Professor at the National University of Córdoba (Argentina), and as a Researcher at Physico-Chemical Research Institute of Córdoba (INFIQC-CONICET). His fields of interest are  the study of metallic nanostructures (such as nanoparticles and nanowires), their formation, and their thermal and electrochemical stability, and include renewable energies (particularly the study of fuel cells and lithium batteries), and computer simulations of complex and non-linear systems.
Silvana G. García is Professor of Chemical Engineering since 2005 at the Universidad Nacional del Sur, Bahía Blanca (Argentina). Her working areas are mainly the electrochemical formationof metallic thin films and nanostructures (nanoparticles, nanowires), involving the nucleation and growth mechanisms, and the analysis of the electrocatalytic effect of such structures for reactions of technological interest.

Ezequiel Leiva is Professor at the National University of Córdoba, Argentina, and Principal Researcher of CONICET, at the Physico-Chemical Research Institute of Córdoba (INFIQC). His main interest is in theoretical aspects of electrochemistry. In recent times, he devoted considerable effort to extend the concept of underpotential deposition to the nanoscale, using nanothermodynamics, statistical mechanics and Monte Carlo simulations. Several of these new concepts are embodied in the present book.

Bibliographic Information

Buy it now

Buying options

eBook USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Other ways to access