Overview
- Overview of synthetic protocols for assembly of functionalized Cp ligands and their transition metal complexes
- Presents recent applications of Cyclopentadienyl (Cp) complexes of transition metals
- Multi-authored volume with contributions from experts in the field
Part of the book series: Topics in Organometallic Chemistry (TOPORGAN, volume 74)
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Keywords
- chiral ferrocenes
- Half-sandwich metallocenes
- transition metal complexes
- Cyclopentadienyl ligands
- C-C bond formation
- C-H activation
- C-C Activation
About this book
This book presents the latest synthetic protocols for the assembly of functionalized
Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes
of transition metals belong to the most important classes of transition metal complexes
with tightly bound ligands in the coordination sphere since their discovery in the middle
of the last century. Even though they have been known for a long time, this field
constantly evolves to deliver novel modified Cp ligands and complexes and to blossom into new
fields of application. Beside the synthesis of ligands and metal complexes this book
concentrates on novel and prospering fields of their application in organic synthesis. In this
respect the Cp complexes have been applied to induce and catalyze various significant chemical
transformations such as new C-C bond formation involving unsaturated substrates (e.g.
cyclotrimerizations, cycloadditions, carbometallations, etc.), C-H bond and C-C bond
activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations,
etc.), as well as many other processes. This volume also covers
the recent development and application of chiral Cp complexes in enantioselective synthesis.
Editors and Affiliations
About the editors
Martin Kotora received a MsC degree in 1986 from Charles University in Prague under the supervision of Dr. Vladimir Sváta and a PhD degree in 1991 from the Institute of Chemical Process Fundamentals, the Czech Academy of Sciences under the supervision of Dr. Milan Hájek. Then he carried out postdoctoral work with Tamotsu Takahashi (1993-1995) at the Institute for Molecular Science (Okazaki, Japan) as a JSPS fellow and later with Ei-ichi Negishi at Purdue University (Indiana, USA). In 1996 he joined the faculty at the Catalysis Research Center, Hokkaido University (Sapporo, Japan) in the rank of associate professor. In autumn 2000 he joined the faculty of Charles Universityin Prague as an assistant professor of chemistry and subsequently was promoted to the ranks of associate professor (2003) and full professor (2006). In 2014 he received Rudolf Lukeš Prize for Achievements in Organic Chemistry from the Czech Chemical Society. His group's research interests center around transition metal complex catalyzed or mediated reactions (e.g. cyclotrimerization and the C-C bond activation), organocatalysis, Dewar benzenes, and their application synthesis of natural and biologically active compounds.
Bibliographic Information
Book Title: Metallocenes in Regio- and Stereoselective Synthesis
Editors: Marko Hapke, Martin Kotora
Series Title: Topics in Organometallic Chemistry
Publisher: Springer Cham
eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)
Copyright Information: The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG 2024
Hardcover ISBN: 978-3-031-57380-4Due: 24 June 2024
Softcover ISBN: 978-3-031-57383-5Due: 24 June 2024
eBook ISBN: 978-3-031-57381-1Due: 24 June 2024
Series ISSN: 1436-6002
Series E-ISSN: 1616-8534
Edition Number: 1
Number of Pages: VII, 204