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Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion II

Homogeneously Catalyzed Transformations, Acrylics from Biomass, Theoretical Aspects, Lignin Valorization and Pyrolysis Pathways

  • Summarizes how homogeneous metal complex catalysts have been applied to the hydrodeoxygenation of sugars, polyalcohols and their derivatives and the associated reaction mechanisms
  • Shows how theoretical approaches help us to understand the mechanisms of catalytic conversions of sugars and their condensation and decomposition pathways
  • Discusses the mechanism of the catalytic dehydration of lactic to acrylic acid, the hydrogenolysis of lignin to reduced aromatics or its oxidation to value-added products
  • Considers important aspects of the mechanisms of biomass pyrolysis and gasification

Part of the book series: Green Chemistry and Sustainable Technology (GCST)

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Table of contents (9 chapters)

  1. Front Matter

    Pages i-x
  2. Deoxydehydration (DODH) of Biomass-Derived Molecules

    • Shuo Liu, Jing Yi, Mahdi M. Abu-Omar
    Pages 1-11
  3. Computational Chemistry of Catalytic Biomass Conversion

    • Guanna Li, Emiel J. M. Hensen, Evgeny A. Pidko
    Pages 63-104
  4. Humin Formation Pathways

    • Jacob Heltzel, Sushil K. R. Patil, Carl R. F. Lund
    Pages 105-118
  5. Catalytic Hydrodeoxygenation of Lignin Model Compounds

    • Basudeb Saha, Ian Klein, Trenton Parsell, Mahdi M. Abu-Omar
    Pages 119-129
  6. Oxidation of Lignins and Mechanistic Considerations

    • Adilson R. Gonçalves, Priscila Benar, Ulf Schuchardt
    Pages 131-144
  7. Pyrolysis Mechanisms of Lignin Model Compounds Using a Heated Micro-Reactor

    • David J. Robichaud, Mark R. Nimlos, G. Barney Ellison
    Pages 145-171
  8. Catalytic Gasification of Lignocellulosic Biomass

    • C. V. Pramod, K. Seshan
    Pages 173-198

About this book

Volume II presents the latest advances in catalytic hydrodeoxygenation and other transformations of some cellulosic platform chemicals to high value-added products. It presents the theoretical evaluation of the energetics and catalytic species involved in potential pathways of catalyzed carbohydrate conversion, pathways leading to the formation of humin-based by-products, and thermal pathways in deriving chemicals from lignin pyrolysis and hydrodeoxygenation. Catalytic gasification of biomass under extreme thermal conditions as an extension of pyrolysis is also discussed.

Marcel Schlaf, PhD, is a Professor at the Department of Chemistry, University of Guelph, Canada.

Z. Conrad Zhang, PhD, is a Professor at the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.

Editors and Affiliations

  • The Guelph-Waterloo-Centre for Graduate Work in Chemistry (GWC)2, Department of Chemistry, University of Guelph, Guelph, Canada

    Marcel Schlaf

  • Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Dalian, China

    Z. Conrad Zhang

About the editors

Prof. Marcel Schlaf graduated as a Diplom-Chemiker from the Bayerische-Julius-Maximilian Universität in Würzburg, Bavaria in 1992. After obtaining a Ph.D. in Inorganic Chemistry from the University of Toronto in 1996, he was an NSERC post-doctoral fellow at the University of Ottawa and at Brookhaven National Laboratory, Long Island, NY. He joined the Department of Chemistry at the University of Guelph in 1999 where he was promoted to the rank of associate professor in 2004 and full professor in 2011. In 1995 and 2006 he was a visiting researcher at Los Alamos National Laboratory, NM and in 2009 a visiting faculty at Peking University and Dalian University of Technology in China. In 2010 he was appointed Adjunct Research Professor at the Department of Chemical and Biochemical Engineering, Faculty of Engineering, University of Western Ontario and the Institute for Chemicals and Fuels from Alternative Resources (ICFAR). His research interests lie in the development of new homogeneous catalysts and processes for the selective deoxygenation of sugars, sugar alcohols and triglycerides to petrochemicals or monomers and the upgrading of pyrolysis bio-oil, as obtained from non-food ligno-cellulosic biomass, to usable fuel using heterogeneous catalysts, notably non-toxic sacrificial catalysts derived from Bauxite mining waste (Red Mud). He has published more than 40 papers and holds 3 patents.

Professor Z. Conrad Zhang received his B.S. in Chemistry from Lanzhou University, China in 1982 and his Ph.D. in Chemistry from the University of Connecticut in 1988. He carried postdoctoral research at Northwestern University on zeolite catalysts and zeolite supported metal catalysts.  He later became a research assistant professor at the Catalysis Center of Northwestern University.  He started his industrial research career in 1992 with Johnson Matthey, and shortly after joined Akzo Nobel’s Central Research as a senior chemist. He became a senior scientist at AkzoNobel and established a multiple-disciplinary research group at the corporate level of Akzo Nobel Chemicals. In 2005, Professor Zhang joined the Pacific Northwest National Lab (PNNL) as a Chief Scientist. He led his research group pioneered the research in the conversion of glucose and cellulose to 5-hydroxymethylfurfural. In 2008, Professor Zhang joined KiOR Inc. as a member of the start-up management team at the position of the Director of Science and R&D of KiOR Inc. Professor Zhang Joined the Dalian Institute of Chemical Physics as a “Thousand Talent Program” full professor since 2013. His research is focused on the conversion of biomass to bio-fuels and bio-chemicals. Dr. Zhang has 90 publications and over 35 patents.

Bibliographic Information

  • Book Title: Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion II

  • Book Subtitle: Homogeneously Catalyzed Transformations, Acrylics from Biomass, Theoretical Aspects, Lignin Valorization and Pyrolysis Pathways

  • Editors: Marcel Schlaf, Z. Conrad Zhang

  • Series Title: Green Chemistry and Sustainable Technology

  • DOI: https://doi.org/10.1007/978-981-287-769-7

  • Publisher: Springer Singapore

  • eBook Packages: Energy, Energy (R0)

  • Copyright Information: Springer Science+Business Media Singapore 2016

  • Hardcover ISBN: 978-981-287-768-0Published: 06 November 2015

  • Softcover ISBN: 978-981-10-1317-1Published: 23 August 2016

  • eBook ISBN: 978-981-287-769-7Published: 30 October 2015

  • Series ISSN: 2196-6982

  • Series E-ISSN: 2196-6990

  • Edition Number: 1

  • Number of Pages: X, 198

  • Number of Illustrations: 100 b/w illustrations, 22 illustrations in colour

  • Topics: Renewable and Green Energy, Catalysis, Biotechnology, Sustainable Development

Buy it now

Buying options

eBook USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Other ways to access