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Functionalization of Carborane via Carboryne Intermediates

  • Book
  • © 2016

Overview

Authors:
  1. Da Zhao

    1. Dept.of Chemi. and State Key Lab. of sy, The Chinese University of Hong Kong, Hong Kong, China

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  • Nominated by The Chinese University of Hong Kong as an outstanding Ph.D. thesis
  • Presents groundbreaking new work in carborane chemistry
  • Inspires future work on synthetic, cluster, and materials chemistry
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (8 chapters)

  1. Front Matter

    Pages i-xvii
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  2. Introduction

    • Da Zhao
    Pages 1-27

  3. Regioselective Insertion of o-Carborynes into α-C−H Bond of Tertiary Amines

    • Da Zhao
    Pages 29-45

  4. Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction

    • Da Zhao
    Pages 47-72

  5. Reaction of o-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition

    • Da Zhao
    Pages 73-85

  6. 1,3-Dehydro-o-Carborane: Generation and Reaction with Arenes

    • Da Zhao
    Pages 87-101

  7. Ene Reaction of 1,3-Dehydro-o-Carborane

    • Da Zhao
    Pages 103-115

  8. Cage Boron Arylation of o-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling

    • Da Zhao
    Pages 117-126

  9. Conclusion

    • Da Zhao
    Pages 127-129

  10. Back Matter

    Pages 131-170
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Keywords

About this book

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis.  

Authors and Affiliations

  • Dept.of Chemi. and State Key Lab. of sy, The Chinese University of Hong Kong, Hong Kong, China

    Da Zhao

About the author


Bibliographic Information

  • Book Title: Functionalization of Carborane via Carboryne Intermediates

  • Authors: Da Zhao

  • Series Title: Springer Theses

  • DOI: https://doi.org/10.1007/978-981-10-1569-4

  • Publisher: Springer Singapore

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: Springer Science+Business Media Singapore 2016

  • Hardcover ISBN: 978-981-10-1568-7Published: 15 June 2016

  • Softcover ISBN: 978-981-10-9389-0Published: 07 June 2018

  • eBook ISBN: 978-981-10-1569-4Published: 04 June 2016

  • Series ISSN: 2190-5053

  • Series E-ISSN: 2190-5061

  • Edition Number: 1

  • Number of Pages: XVII, 170

  • Number of Illustrations: 121 b/w illustrations, 5 illustrations in colour

  • Topics: Organic Chemistry, Physical Chemistry, Catalysis

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