Skip to main content
SpringerLink
Log in
Book cover

Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations

  • Book
  • © 2000

Overview

Editors:
  1. Bernard Meunier

    1. Laboratoire de Chimie de Coordination du CNRS, Toulouse Cedex 4, France

    View editor publications

    You can also search for this editor in PubMed   Google Scholar

  • This series presents critical reviews of the present position and future trends in modern chemical research
  • Short and concise reports on chemistry, each written by the world's renowned experts. Still valid and useful after 5 or 10 years. More information as well as the electronic version of the whole content available at: http://link.springer.de/series/sb/
  • Includes supplementary material: sn.pub/extras

Part of the book series: Structure and Bonding (STRUCTURE, volume 97)

This is a preview of subscription content, log in via an institution to check access.

Access this book

Log in via an institution
eBook USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Other ways to access

Licence this eBook for your library

Institutional subscriptions

Table of contents (10 chapters)

  1. Front Matter

    Pages I-IX
    Download chapter PDF

  2. Active Iron-Oxo and Iron-Peroxo Species in Cytochromes P450 and Peroxidases; Oxo-Hydroxo Tautomerism with Water-Soluble Metalloporphyrins

    • Bernard Meunier, Jean Bernadou
    Pages 1-35

  3. Nucleophilicity of Iron-Peroxo Porphyrin Complexes

    • Diana L. Wertz, Joan Selverstone Valentine
    Pages 37-60

  4. Characterization of High-Valent Oxo-Metalloporphyrins

    • Yoshihito Watanabe, Hiroshi Fujii
    Pages 61-89

  5. Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase

    • Detlef Schröder, Helmut Schwarz, Sason Shaik
    Pages 91-123

  6. Quantum Chemical Studies on Metal-Oxo Species Related to the Mechanisms of Methane Monooxygenase and Photosynthetic Oxygen Evolution

    • P. E. M. Siegbahn, Robert H. Crabtree
    Pages 125-144

  7. Characterization and Properties of Non-Heme Iron Peroxo Complexes

    • Jean-Jacques Girerd, Frédéric Banse, Ariane Jalila Simaan
    Pages 145-177

  8. Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases

    • Allan G. Blackman, William B. Tolman
    Pages 179-211

  9. Rhenium-Oxo and Rhenium-Peroxo Complexes in Catalytic Oxidations

    • Fritz E. Kühn, Wolfgang A. Herrmann
    Pages 213-236

  10. Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes

    • Waldemar Adam, Catherine M. Mitchell, Chantu R. Saha-Möller, Oliver Weichold
    Pages 237-285

  11. Nature of Activated Bleomycin

    • Richard M. Burger
    Pages 287-303

  12. Back Matter

    Pages 305-323
    Download chapter PDF
Back to top

Keywords

About this book

The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.

Editors and Affiliations

  • Laboratoire de Chimie de Coordination du CNRS, Toulouse Cedex 4, France

    Bernard Meunier

Bibliographic Information

Publish with us

Policies and ethics

Back to top

Search

Navigation