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Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance

  • Book
  • © 2016

Overview

  • Study in Natural Science
  • Includes supplementary material: sn.pub/extras

Part of the book series: BestMasters (BEST)

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Table of contents (4 chapters)

Keywords

About this book

Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the nth order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. 

Authors and Affiliations

  • Zurich, Switzerland

    Janne Marie Soetbeer

About the author

Janne Marie Soetbeer completed her Master’s Thesis at the Swiss Federal Institute of Technology in Zurich, Switzerland. After a research stay with Prof. Dr. Robert Griffin at the Massachusetts Institute of Technology in Cambridge, USA, she will be returning to Zurich to start her PhD in Prof. Dr. Gunnar Jeschke’s group.

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