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Multifunctional Mesoporous Inorganic Solids

  • Book
  • © 1993

Overview

Editors:
  1. César A. C. Sequeira

    1. Instituto Superior Técnico, Universidade Técnica de Lisboa, Lisboa, Portugal

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  2. Michael J. Hudson

    1. Department of Chemistry, University of Reading, Reading, UK

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    You can also search for this editor in PubMed   Google Scholar

Part of the book series: Nato Science Series C: (ASIC, volume 400)

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Table of contents (36 chapters)

  1. Front Matter

    Pages i-xxvii
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  2. The Measurement of Porosities

    1. Front Matter

      Pages 1-1
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    2. The Measurement of Mesoporosity

      • Charis R. Theocharis
      Pages 3-18

    3. About Surface Area and Porosity Measurements in Pillared Clays

      • F. Bergaya, L. Gatineau, H. Van Damme
      Pages 19-26

    4. New Theoretical Approaches to Characterization of Mesoporous Solids

      • A. V. Neimark
      Pages 27-35

    5. Nitrogen Adsorption on Zirconium Bis Monohydrogenphosphate with α-Type Structure

      • F. Marmottini
      Pages 37-48

    6. Study of the Accessible Micropore Volume in Pillared Montmorillonites

      • M. D. Alba, R. Alvero, M. A. Castro, J. M. Trillo
      Pages 49-53

  3. Porous Crystalline Materials

    1. Front Matter

      Pages 55-55
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    2. Hydrothermal Synthesis and Porous Crystals

      • R. M. Barrer
      Pages 57-71

    3. Pores in Tetrahedral Frameworks

      • P. Behrens
      Pages 73-97

    4. Realistic Simulation of Mesoporous Materials by Random Packing Arrays of Hard Spheres

      • N. H. Pantelis
      Pages 99-105

    5. Synthesis and Characterization of Vanadium Oxide Layered Compound

      • N. Ulagappan, V. Krishnasamy
      Pages 107-110

    6. SHS-The New Method of Different Inorganic Materials Production

      • K. L. Padukov
      Pages 111-120

    7. Treatment of Dehydrated Na-Y Zeolite with the Heteropolymetallic Products of Transmetalation Reactions

      • Tarek M. Abdel-Fattah, Geoffrey Davies
      Pages 121-126

    8. Textural Characterization of Pilc Montmorillonite Pillared with Binary Oxides LaNiOx

      • S. P. Skaribas, P. J. Pomonis, P. Grange, B. Delmon
      Pages 127-136

    9. Structure Direction in Zeolite Synthesis

      • D. E. W. Vaughan
      Pages 137-156
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Keywords

About this book

1. Introduction. There is much interest in the general subject of porous inorganic materials with respect to their use as sorbents or catalysts. Such inorganic solids may be microporous, mesoporous or macroporous according to the sizes of the pores within the solid. Often there is a range of pore sizes within any given solid and so there is special interest in the synthesis, characterisation and application of porous inorganic solids with well defined pores. Pores of diameter larger than 50 nm are generally termed macropores. Those with diameters of less than 2 nm are micropores and pores of intermediate size are called mesopores. Solids, which contain only mesopores, are correctly called mesoporous but very often there is a combination of different types of porosities within one given solid. The synthesis, characterisation and application of microporous solids is much more advanced than is the case with mesoporous substances. Moreover, the synthesis of crystalline mesoporous materials is one clear goal for the future but which has not been attained so far. Consequently, it is of interest to examine the current state of our knowledge of microporous materials and to examine how this may apply to mesoporous materials. Both catalytic and sorption processes could benefit from studies of mesoporous solids because the mesopores could permit diffusion of larger reactants or products than is the case in microporous materials. 2.

Editors and Affiliations

  • Instituto Superior Técnico, Universidade Técnica de Lisboa, Lisboa, Portugal

    César A. C. Sequeira

  • Department of Chemistry, University of Reading, Reading, UK

    Michael J. Hudson

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