Organometallic Compounds

1. Front Matter

   Pages i-xiii

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2. Introduction to Volume Two

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 1-6

3. Two-electron ligands

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 7-38

4. Three-electron ligands

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 39-64

5. Four-electron ligands

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 65-89

6. Five-electron ligands

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 90-164

7. Six-electron ligands

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 165-189

8. Seven-electron ligands, mixed sandwich complexes, related azulene derivatives and cyclo-octatetraene complexes

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 190-202

9. One-electron ligands

   • G. E. Coates, M. L. H. Green, K. Wade

   Pages 203-287

10. Organometallic complexes formed from acetylenes

    • G. E. Coates, M. L. H. Green, K. Wade

    Pages 288-311

11. The role of organotransition metal complexes in some catalytic reactions

    • G. E. Coates, M. L. H. Green, K. Wade

    Pages 312-348

12. Back Matter

    Pages 349-376

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to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.

• chromium
• copper
• gold
• manganese
• metals
• molybdenum
• nickel
• olefine
• organometallic chemistry
• palladium
• platinum
• rhodium
• silver
• titanium
• transition metal

• University of Durham, USA

  G. E. Coates, K. Wade

• Balliol College, Oxford, UK

  M. L. H. Green

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