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Organometallic Compounds

Volume Two: The Transition Elements

  • Book
  • © 1968

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Authors:
  1. G. E. Coates

    1. University of Durham, USA

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  2. M. L. H. Green

    1. Balliol College, Oxford, UK

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  3. K. Wade

    1. University of Durham, USA

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Table of contents (10 chapters)

  1. Front Matter

    Pages i-xiii
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  2. Introduction to Volume Two

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 1-6

  3. Two-electron ligands

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 7-38

  4. Three-electron ligands

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 39-64

  5. Four-electron ligands

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 65-89

  6. Five-electron ligands

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 90-164

  7. Six-electron ligands

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 165-189

  8. Seven-electron ligands, mixed sandwich complexes, related azulene derivatives and cyclo-octatetraene complexes

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 190-202

  9. One-electron ligands

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 203-287

  10. Organometallic complexes formed from acetylenes

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 288-311

  11. The role of organotransition metal complexes in some catalytic reactions

    • G. E. Coates, M. L. H. Green, K. Wade
    Pages 312-348

  12. Back Matter

    Pages 349-376
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Keywords

About this book

to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.

Authors and Affiliations

  • University of Durham, USA

    G. E. Coates, K. Wade

  • Balliol College, Oxford, UK

    M. L. H. Green

Bibliographic Information

  • Book Title: Organometallic Compounds

  • Book Subtitle: Volume Two: The Transition Elements

  • Authors: G. E. Coates, M. L. H. Green, K. Wade

  • DOI: https://doi.org/10.1007/978-94-011-6893-9

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: M. L. H. Green 1968

  • Softcover ISBN: 978-94-011-6895-3Published: 13 November 2013

  • eBook ISBN: 978-94-011-6893-9Published: 06 December 2012

  • Edition Number: 1

  • Number of Pages: XIII, 376

  • Number of Illustrations: 138 b/w illustrations

  • Topics: Science, Humanities and Social Sciences, multidisciplinary

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