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Radicals on Surfaces

  • Book
  • © 1995

Overview

Editors:
  1. Anders Lund
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    You can also search for this editor in PubMed   Google Scholar

  2. Christopher J. Rhodes
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    You can also search for this editor in PubMed   Google Scholar

Part of the book series: Topics in Molecular Organization and Engineering (MOOE, volume 13)

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Table of contents (11 chapters)

  1. Front Matter

    Pages i-ix
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  2. Properties of Catalytic Surfaces

    1. Front Matter

      Pages 1-1
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    2. EPR Characterization of Oxide Supported Transition Metal Ions: Relevance to Catalysis

      • Catherine Louis, Christine Lepetit, Michel Che
      Pages 3-38

    3. Study of Catalytic Site Structure and Diffusion of Radicals in Porous Heterogenous Systems with ESR, ENDOR and ESE

      • R. I. Samoilova, A. D. Milov, Yu. D. Tsvetkov
      Pages 39-59

    4. Theoretical Studies of Core Ionization, Excitation and De-excitation of Adsorbates

      • Masahide Ohno
      Pages 61-86

  3. Structure and Reactivity of Radicals on Surfaces

    1. Front Matter

      Pages 87-87
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    2. Electron Magnetic Resonance of Aromatic Radicals on Metal Oxide Surfaces

      • R. B. Clarkson, Karen Mattson, Wenjun Shi, Wei Wang, R. L. Belford
      Pages 89-117

    3. ESR Studies of Organic Radical Cations in Zeolites

      • Christopher J. Rhodes, Chantal S. Hinds
      Pages 119-145

    4. Surface Trapped Electrons on Metal Vapour Modified Magnesium Oxide. Nature of the Surface Centres and Reactivity with Adsorbed Molecules

      • Elio Giamello, Damien Murphy
      Pages 147-177

    5. Radicals on Surfaces Formed by Ionizing Radiation

      • Masaru Shiotani, Mikael Lindgren
      Pages 179-199

    6. Photostimulated Formation of Radicals on Oxide Surfaces

      • Alexander M. Volodin, Vadim A. Bolshov, Tatiana A. Konovalova
      Pages 201-226

  4. Trends in Modern Techniques

    1. Front Matter

      Pages 227-227
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    2. Fourier Transform Electron Paramagnetic Resonance Studies of Photochemical Reactions in Heterogeneous Media

      • Hans Van Willigen, Patricia R. Levstein
      Pages 229-257

    3. Muon Spin Resonance of Radicals on Surfaces

      • Emil Roduner, Martina Schwager, Mee Shelley
      Pages 259-276

    4. Investigation of Radical Ions with Time-Resolved Surface Enhanced Raman Spectroscopy

      • Ronald L. Birke, John R. Lombardi
      Pages 277-310

  5. Back Matter

    Pages 311-318
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Keywords

About this book

Studies of free radicals on surfaces are of interest for several reasons: the spontaneous or stimulated formation of radicals from adsorbed molecules may represent one possible mechanism for heterogeneous catalysis. In some cases the radicals are ionic, indicating that primary oxidation and reduction reactions occur. Radicals can also be used as probes to investigate diffusion processes on catalytic surfaces. The first direct observations were made more than 30 years ago, but detailed studies of structure, reactions and mobility have only recently become feasible with the advent of powerful spectroscopic techniques, to a great extent developed and used by the contributors to this volume.
This comprehensive review describes new trends in the field. Leading experts write about the nature of surface active sites, methods to identify them, and the radicals formed from adsorbed molecules interacting with the surface. The emphasis is on the fundamentals covering thermal, photostimulated and radiation induced reactions as well as diffusion processes. This provides the necessary background for technological applications.
This book will be useful to those who are interested in surface chemistry, heterogeneous catalysis as well as those who want to study reactive intermediates in chemical reactions. It is also of interest to scientists in photo and radiation physics and chemistry.

Bibliographic Information

  • Book Title: Radicals on Surfaces

  • Editors: Anders Lund, Christopher J. Rhodes

  • Series Title: Topics in Molecular Organization and Engineering

  • DOI: https://doi.org/10.1007/978-94-011-0493-7

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer Science+Business Media Dordrecht 1995

  • Hardcover ISBN: 978-0-7923-3108-7Published: 31 January 1995

  • Softcover ISBN: 978-94-010-4221-5Published: 11 October 2012

  • eBook ISBN: 978-94-011-0493-7Published: 06 December 2012

  • Series ISSN: 0927-0817

  • Edition Number: 1

  • Number of Pages: IX, 318

  • Topics: Catalysis, Physical Chemistry

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