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Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization

  • Book
  • © 1990

Overview

Editors:
  1. M. Aresta

    1. Department of Chemistry, University of Bari, Bari, Italy

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  2. J. V. Schloss

    1. Central Research & Development Department, E.I. du Pont de Nemours & Co., Wilmington, USA

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    You can also search for this editor in PubMed   Google Scholar

Part of the book series: Nato Science Series C: (ASIC, volume 314)

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Table of contents (23 chapters)

  1. Front Matter

    Pages i-xi
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  2. Utilization of Carbon Dioxide as a Source of Carbon: a Challenge of Great Intellectual Significance for Scientists

    • Michele Aresta
    Pages 1-18

  3. Market and Application of Merchant CO2

    • Paolo Graziano
    Pages 19-22

  4. Theoretical Studies of Carbon Dioxide Organometallic Reactivity

    • A. Dedieu, C. Bo, F. Ingold
    Pages 23-42

  5. The Organometallic Chemistry of Carbon Dioxide Pertinent to Catalysis

    • Donald J. Darensbourg
    Pages 43-64

  6. Catalytic Incorporation of CO2 for the Synthesis of Organic Compounds

    • Pierre H. Dixneuf, Christian Bruneau, Jean Fournier
    Pages 65-77

  7. Photoreduction of carbon dioxide to formate and photo-oxidation of carbon monoxide to carbon dioxide by the use of transition metal complexes and visible light

    • Raymond Ziessel
    Pages 79-100

  8. Electrochemical Syntheses Involving Carbon Dioxide

    • Giuseppe Silvestri, Salvatore Gambino, Giuseppe Filardo
    Pages 101-127

  9. Mammalian and Plant Carbonic Anhydrases: Structure, Function, Mechanism and Control

    • Y. Pocker
    Pages 129-143

  10. Carbonic Anhydrases: The Mechanistic, Spectroscopic, and Model Studies

    • R. S. Brown
    Pages 145-180

  11. The Mechanism of Action of Carbonic Anhydrase

    • L. Banci, I. Bertini, C. Luchinat, J. M. Moratal
    Pages 181-197

  12. Computer Simulation of Zinc-Containing Enzymes

    • Kenneth M. Merz Jr.
    Pages 199-209

  13. Mechanism of Carboxylation by Biotin Enzymes

    • Albert S. Mildvan, David C. Fry, Engin H. Serpersu
    Pages 211-219

  14. Carbamate Synthases and Kinases

    • Vicente Rubio, Hubert G. Britton, Leandro B. Rodriguez-Aparicio, Isabel Climent
    Pages 221-238

  15. Carboxyphosphate; Predicted Chemical Properties, Synthesis and Role as an Intermediate in Enzymic Reactions

    • W. B. Knight
    Pages 239-258

  16. Biological Utilization of Carbon Dioxide. Enzymic Catalysis Patterns Involving Biotin, ATP, and Bicarbonate

    • Ronald Kluger
    Pages 259-271

  17. Chemical Roles of B12-Derivatives in the Bacterial C1-Metabolism

    • Bernhard Kräutler
    Pages 273-292

  18. One-Carbon Metabolism of Anaerobic Bacteria: Challenge for Chemistry

    • Georg Fuchs
    Pages 293-300

  19. Increasing Photosynthesis by Genetic Manipulation: Difficulties and Prospects

    • Mirta N. Sivak
    Pages 301-320

  20. The Kinetic Properties of Ribulosebisphosphate Carboxylase

    • John V. Schloss
    Pages 321-345
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Keywords

About this book

The activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the role of these reaction types in both homogeneous and heterogenous catalytic processes leading to useful chemicals will be elaborated. _OM> (1) lMt-H + ~ lMlopi _OM> (2) [Mt-R + C0. 2 [M]0. 2CR _OM> (3) [Mt-OR+ ~ [M]0. 2COR _OM> (4) [Mt-NR2 + C0. 2 [M]~CNR2 Insertion of C02 into the Metal-Hydride Bond. The reaction of anionic group 6 (Cr. Mo. W) transition metal hydrides with carbon dioxide to afford metalloformates occurs readlly at ambient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases of C02 insertion into the metal hydride bond to provide the alternative. metallocarboxylic acid. isomer (referred in Scheme 1 as abnormal). 3 Recent theoretical studies ascribe this preference to an unfavorable electrostatic interaction and poorer orbital overlap in the latter pro­ 4 cess. Nevertheless.

Editors and Affiliations

  • Department of Chemistry, University of Bari, Bari, Italy

    M. Aresta

  • Central Research & Development Department, E.I. du Pont de Nemours & Co., Wilmington, USA

    J. V. Schloss

Bibliographic Information

  • Book Title: Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization

  • Editors: M. Aresta, J. V. Schloss

  • Series Title: Nato Science Series C:

  • DOI: https://doi.org/10.1007/978-94-009-0663-1

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: Kluwer Academic Publishers 1990

  • Hardcover ISBN: 978-0-7923-0871-3Due: 31 August 1990

  • Softcover ISBN: 978-94-010-6783-6Published: 22 January 2012

  • eBook ISBN: 978-94-009-0663-1Published: 06 December 2012

  • Series ISSN: 1389-2185

  • Edition Number: 1

  • Number of Pages: 452

  • Topics: Inorganic Chemistry, Biochemistry, general, Plant Physiology, Organic Chemistry

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