Chemically Induced Magnetic Polarization

1. Front Matter

   Pages I-XII

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2. Introduction to Chemically Induced Magnetic Polarization

   • R. Kaptein

   Pages 1-16

3. CIDNP Exhibited by Thermally Decomposing Diacyl Peroxides

   • R. G. Lawler

   Pages 17-28

4. Time-Dependence of CIDNP Intensities

   • R. G. Lawler

   Pages 29-37

5. Chemically Induced Nuclear Spin Polarization in Photo-Initiated Radical Ion Reactions

   • Heinz D. Roth

   Pages 39-76

6. Radical Pair Mechanism of Chemically Induced Magnetic Polarization

   • F. J. Adrian

   Pages 77-105

7. Experimental Observation of Electron Spin Polarization in Reactions

   • K. A. McLauchlan

   Pages 107-118

8. Chemically Induced Electron Polarization of Radiolytically Produced Radicals

   • Richard W. Fessenden

   Pages 119-150

9. Flash-Photolysis Electron Spin Resonance

   • K. A. McLauchlan

   Pages 151-167

10. Time-Dependence of ESR Intensities

    • J. Boiden Pedersen

    Pages 169-180

11. Photochemical Processes

    • P. W. Atkins

    Pages 181-190

12. The Triplet Mechanism

    • P. W. Atkins

    Pages 191-203

13. Light Modulated Cidep Experiments

    • L. T. Muus

    Pages 205-224

14. Low-Field Effects and CIDNP of Biradical Reactions

    • G. L. Closs

    Pages 225-256

15. Pair Substitution Effects In CIDNP

    • R. Kaptein

    Pages 257-266

16. CIDNP from Bimolecular Reactions of Organometallic Compounds

    • R. G. Lawler

    Pages 267-274

17. The Problem of Parallel Radical and Non-Radical Mechanisms

    • R. G. Lawler

    Pages 275-281

18. Effects of Diffusion on Reaction Rates

    • J. Boiden Pedersen

    Pages 283-296

19. General Relations for High Field CIDNP

    • J. Boiden Pedersen

    Pages 297-308

20. Numerical Methods and Model Dependence in Chemically-Induced Dynamic Spin Polarization

    • Jack H. Freed

    Pages 309-355

Magnetic resonance has constantly been able to surprise with its ability to exhibit new phenomena. Just when it appears to be entering a quiet middle age it bursts into activity with some new manifestation of its versatility. This happened a few years ago, when observations on anomalous intensities were looked at more closely, and the pursuit of explanations and further evidence laid the foundations of the subjects treated in this volume. In organizing the NATO Advanced Study Institute we attempted to bring together a number, but by no means all, of those who had contributed significantly to the subject, and to obtain from them a comprehensive and detailed exposition of the subject. We were particularly anxious to avoid a set of lectures that dealt solely with the theory of the subject, because much of the interest in chemically induced magnetic polarization is due to its usefulness in applications to chemical problems: it is a real chemical tech­ nique, not just an amusing diversion for theoreticians. We set about organizing the course with the idea of making it useful to people who wanted to use the technique (for, after all, in the case of nuclear polarization, CIDNP, the technique can be used in any laboratory with minor modification of standard equipment).

• Chemical reaction
• Diffusion
• magnetic field
• metals
• reactions
• spin

• Aarhus University, Denmark

  L. T. Muus

• Oxford University, UK

  P. W. Atkins, K. A. McLauchlan

• Odense University, Denmark

  J. B. Pedersen

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