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Mo Molybdenum

  • Book
  • © 1989

Overview

Authors:
  1. Hermann Jehn

    1. Forschungsinstitut für Edelmetalle und Metallchemie Schwäbisch Gmünd, Germany

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  2. Wolfgang Kurtz

    1. Gmelin-Institut, Frankfurt am Main, Germany

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  3. Dietrich Schneider

    1. Gmelin-Institut, Frankfurt am Main, Germany

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  4. Ursula Trobisch

    1. Gmelin-Institut, Frankfurt am Main, Germany

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  5. Joachim Wagner

    1. Gmelin-Institut, Frankfurt am Main, Germany

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Editors:
  1. Hartmut Katscher
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  2. Wolfgang Kurtz
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  3. Friedrich Schröder
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Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition (GMELIN, volume M-o / A-B / B / 5)

Part of the book sub series: Mo. Molybdän. Molybdenum (System-Nr. 53) (1039)

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Table of contents (3 chapters)

  1. Front Matter

    Pages I-XVII
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  2. Molybdenum and Nitrogen

    • Hermann Jehn
    Pages 1-66

  3. Molybdenum and Fluorine

    • Hermann Jehn, Wolfgang Kurtz, Dietrich Schneider, Ursula Trobisch, Joachim Wagner
    Pages 67-243

  4. Molybdenum and Chlorine

    • Hermann Jehn, Wolfgang Kurtz, Dietrich Schneider, Ursula Trobisch, Joachim Wagner
    Pages 244-389

  5. Back Matter

    Pages 390-391
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Keywords

About this book

In the first part of this volume the nitrogen-containing compounds of molybdenum are described. The Mo-N system shows that M0 N and MoN are the stable nitrides. MOlybdenum 2 metal dissolves nitrogen to some extent but only at high temperatures. To get better insight into the reactions between nitrogen and molybdenum, the solubility, diffusion, adsorption and desorption phenomena, and ion bombardment are included in the section of the Mo-N system. M0 N has a large range of homogeneity toward lower nitrogen concentrations. The black 2 hexagonal MoN has only a narrow range of homogeneity. In addition some molybdenum compounds containing nitrogen and oxygen are known. The second part contains a full description of the compounds of molybdenum with fluorine. The fluorides MoF n with n ~ 2 are metastable while those with n = 3 to 6 are stable and have been observed in the Mo-F system. Pure MoF can exist without traces of oxygen, in co nt rast 3 to earlier assumptions. MoF was unambigously prepared and characterized in 1957. Its crystal 4 structure is still unknown. MoF is often contaminated with the oxide fluoride MoOF and it is s 4 difficult to remove. Even sm all amounts affect the properties of MoF . MoF , which is liquid at s 6 room temperature and solidifies to a "plastic" crystal modification below ca. 17SC, is the most investigated of all the molybdenum fluorides.

Authors and Affiliations

  • Forschungsinstitut für Edelmetalle und Metallchemie Schwäbisch Gmünd, Germany

    Hermann Jehn

  • Gmelin-Institut, Frankfurt am Main, Germany

    Wolfgang Kurtz, Dietrich Schneider, Ursula Trobisch, Joachim Wagner

Bibliographic Information

  • Book Title: Mo Molybdenum

  • Authors: Hermann Jehn, Wolfgang Kurtz, Dietrich Schneider, Ursula Trobisch, Joachim Wagner

  • Editors: Hartmut Katscher, Wolfgang Kurtz, Friedrich Schröder

  • Series Title: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition

  • DOI: https://doi.org/10.1007/978-3-662-06327-9

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1989

  • eBook ISBN: 978-3-662-06327-9Published: 11 November 2013

  • Edition Number: 8

  • Number of Pages: XVII, 391

  • Number of Illustrations: 3 b/w illustrations

  • Topics: Chemistry/Food Science, general

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