Overview
- Authors:
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Alexandr I. Gusev
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Ural Division of the Russian Academy of Sciences, Institute of Solid State Chemistry, Ekaterinburg, Russia
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Andrej A. Rempel
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Ural Division of the Russian Academy of Sciences, Institute of Solid State Chemistry, Ekaterinburg, Russia
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Andreas J. Magerl
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Lehrstuhl für Kristallographie und Strukturphysik, Universität Erlangen-Nürnberg, Erlangen, Germany
- This book deals with an important topic in materials science, the influence of stoichiometry and order/disorder on material properties
- It summarizes the knowledge available in a comprehensive way
- Includes supplementary material: sn.pub/extras
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Table of contents (11 chapters)
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 1-10
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 11-42
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 43-112
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 113-178
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 179-245
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 247-270
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 271-298
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 299-331
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 333-370
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 371-451
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- Alexandr I. Gusev, Andrej A. Rempel, Andreas J. Magerl
Pages 453-601
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Back Matter
Pages 603-608
About this book
long to understand that the phenomena associated with the redistribution of interstitial atoms and structural vacancies in non stoichiometric compounds represent an excellent model of analogous phenomena arising in solid-state systems with mutual substitution of components. Therefore methods of analysis and description proposed and developed for nonstoichiometric compounds are applicable to a number of systems with substitutional disorder. In 1980, when we embarked on this work, ordering in nonstoichiometric compounds was assumed to be a rare and accidental effect, which hardly deserved close attention. Now many people understand that ordering represents a general regular phenomenon in all non stoichiometric compounds. Ordering effects, which were not even mentioned, or were referred to as something insignificant and negligible just 20 years ago, proved to be numerous and comparable in magnitude with the change of properties in the whole homogeneity interval of non stoichiometric compounds. Phase diagrams of binary systems of transition metals with carbon and nitrogen, which remained unchanged from the time they were plotted in 1950-60s and containing one or two nonstoichiometric compounds, were enriched with many ordered phases. Unfortunately, the accumulated experimental and theoretical knowledge has not so far been disseminated widely.
