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Dipolar Correlation Spectroscopy

Higher-Order Correlation Terms in Three-Spin Double Electron-Electron Resonance (DEER)

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  • © 2015

Overview

  • Publication in the field of natural sciences
  • Includes supplementary material: sn.pub/extras

Part of the book series: BestMasters (BEST)

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Table of contents (6 chapters)

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About this book

Bettina Basel presents experimental conditions which allow to extract the three-spin contribution precisely from experimental multi-spin double electron-electron resonance (DEER) signals. The theory and concepts behind the used techniques, which are among others broadband chirp pump pulses, over coupling of microwave resonators and echo reduction measurements, are discussed and explained in detail. Moreover the setup and results of DEER experiments with newly introduced double chirp pump pulses consisting of two separate chirps are shown. Particular attention is paid to the phenomenon of orientation selection and the concept of orthogonal spin labeling.

Authors and Affiliations

  • FAU Erlangen-Nürnberg Lehrstuhl für Physikalische Chemie I, Erlangen, Germany

    Bettina Basel

About the author

Bettina Basel received her master’s degree in chemistry at Friedrich-Alexander University in Erlangen. Her master’s thesis was written during an ERASMUS stay at ETH Zurich under the supervision of Prof. Dr. Gunnar Jeschke.

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