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One-Dimensional Organometallic Materials

An Analysis of Electronic Structure Effects

  • Book
  • © 1987

Overview

Authors:
  1. M. C. Böhm

    1. Institut für Physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt, Darmstadt, Deutschland

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    You can also search for this author in PubMed   Google Scholar

Part of the book series: Lecture Notes in Chemistry (LNC, volume 45)

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Table of contents (17 chapters)

  1. Front Matter

    Pages N2-V
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  2. Introduction and Historical Review

    1. Introduction and Historical Review

      • M. C. Böhm
      Pages 1-9

  3. Back Matter

    Pages 10-11
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  5. Back Matter

    Pages 38-39
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  7. Back Matter

    Pages 103-107
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  8. Model Calculations in the Framework of a (Semiempirical) Crystal Orbital Approach

    1. Neighborstrand Interactions in One-Dimensional Tight-Binding Models. The (Tetrathiosquarato)nickel(II) System

      • M. C. Böhm
      Pages 108-118

    2. Band-Structure Properties of One-Dimensional Polydecker Sandwich Systems

      • M. C. Böhm
      Pages 119-130

    3. Partially Oxidized Transition-Metal Polymers; Stabilization of Mixed Valence States

      • M. C. Böhm
      Pages 131-141

    4. The Band Structure of One-Dimensional (Tetrazaporphyrinato) - Cobalt(II)

      • M. C. Böhm
      Pages 142-147

    5. The Band Structure of the One-Dimensional (Bisglyoximato)Ni(II) System

      • M. C. Böhm
      Pages 148-155

    6. Band Structures of 1D (Porphyrinato)Ni(II) Systems

      • M. C. Böhm
      Pages 156-163

    7. The 1D Band Structure of Tetrathiotetracene

      • M. C. Böhm
      Pages 164-167

    8. The Band Structure of Polyferrocenylene

      • M. C. Böhm
      Pages 168-171
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Keywords

About this book

This lecture note gives an analysis of electronic structure effects for a new class of molecular solids, i. e. one-dimensional organometal­ lic systems formed by transition-met. l atoms that are embedded in a matrix of macrocyclic organic ligands. These systems as well as orga­ nic metals have focused considerable interest due to the potential formation of high-mobility charge carriers. For the present author it is difficult to participate in this restriction on a single physical property (i. e. high electronic conductivities, technical applications, etc. ). The lecture note is hopefully a small contribution to enhance the general understanding of certain electronic properties in organo­ metallic polymers. Those problems have been considered in the first place that seem to form a theoretical deficit in one specific field of solid-state chemistry. For the reader it will become evident that this contribution is a compromise always guided and limited by boundaries: i) An attempt to present problems to a ·chemical· audience which have their roots in solid-state physics. ii) The model calculations are limited by the currently available computational facilities. This ·boundary· implies that the compu­ tational data a~e subject to severe theoretical approximations. iii) Theorists have often a strong tendency to identify their numeri­ cal results and models with physical effects. Also this lecture note is not free of this almost universal trend. Nevertheless the author hopes that this text leads to some insight into a rather modern research field. M. e. B6hm I.

Authors and Affiliations

  • Institut für Physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt, Darmstadt, Deutschland

    M. C. Böhm

Bibliographic Information

  • Book Title: One-Dimensional Organometallic Materials

  • Book Subtitle: An Analysis of Electronic Structure Effects

  • Authors: M. C. Böhm

  • Series Title: Lecture Notes in Chemistry

  • DOI: https://doi.org/10.1007/978-3-642-93351-6

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1987

  • Softcover ISBN: 978-3-540-17216-1Published: 24 June 1987

  • eBook ISBN: 978-3-642-93351-6Published: 06 December 2012

  • Series ISSN: 0342-4901

  • Series E-ISSN: 2192-6603

  • Edition Number: 1

  • Number of Pages: V, 181

  • Topics: Theoretical and Computational Chemistry, Inorganic Chemistry

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