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The Barbier Reaction and Related One-Step Processes

  • Book
  • © 1993

Overview

Authors:
  1. Cornelis Blomberg

    1. Abcoude, The Netherlands

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Part of the book series: Reactivity and Structure: Concepts in Organic Chemistry (REACTIVITY, volume 31)

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Table of contents (5 chapters)

  1. Front Matter

    Pages I-XIII
    Download chapter PDF

  2. Introduction

    • Cornelis Blomberg
    Pages 1-13

  3. Synthetic Applications of the Barbier Reaction

    • Cornelis Blomberg
    Pages 14-74

  4. Barbier-Type Reactions with Other Metals

    • Cornelis Blomberg
    Pages 75-136

  5. The Mechanism of the Barbier Reaction

    • Cornelis Blomberg
    Pages 137-165

  6. Experimental Procedures for Barbier Reactions

    • Cornelis Blomberg
    Pages 166-183
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Keywords

About this book

The significant increase in applications of Barbier and Barbier-type reactions in (in-) organic synthesis over the past twenty-five years, combined with repeated stimulation on the part of Springer-Verlag (Dr. R. Stumpe) were strong in­ centives for me to write this book. My earliest activities in this field include a modest and first-ever review article (in cooperation with Dr. F. A. Hartog who at that time (1977) did his doctoral research on the Barbier reaction). References to this review article, as mentioned in the Science Citation Index till recently are a good indication for a continued interest in this simple synthetic procedure. The subtitle of this monograph, Related One-Step Processes, may require the following clarification. A synthesis with the aid of an organometallic compound is usually carried out in two steps: 1) the organometallic reagent is prepared from an organo halide and a metal in a solvent, 2) a chosen substrate is added to this reagent. In a Barbier reaction these two steps are combined: a mixture of the organo halide and the substrate is added to a suspension of the metal-in an appropriate solvent.

Authors and Affiliations

  • Abcoude, The Netherlands

    Cornelis Blomberg

Bibliographic Information

  • Book Title: The Barbier Reaction and Related One-Step Processes

  • Authors: Cornelis Blomberg

  • Series Title: Reactivity and Structure: Concepts in Organic Chemistry

  • DOI: https://doi.org/10.1007/978-3-642-85019-6

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1993

  • Hardcover ISBN: 978-3-540-57169-8Due: 16 December 1993

  • Softcover ISBN: 978-3-642-85021-9Published: 11 January 2012

  • eBook ISBN: 978-3-642-85019-6Published: 06 December 2012

  • Series ISSN: 0341-2377

  • Edition Number: 1

  • Number of Pages: XIII, 183

  • Topics: Organic Chemistry

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