Interactions of Water in Ionic and Nonionic Hydrates

1. Front Matter

   Pages I-XIII

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2. Hydration of Ions

   1. Interactions of Water in Ionic Hydrates

      • K. Heinzinger, G. Pálinkás

      Pages 1-22

   2. The Determination of Vibrational Frequencies in H-Bonded Liquids from Molecular Dynamics Simulations

      • Philippe Bopp

      Pages 23-26

   3. A Model of Ion Hydration

      • D. Bratko, L. Blum, D. Q. Wei

      Pages 27-31

   4. Infrared Spectroscopic Study on Anion-Hydration in CH2Cl2

      • H. Kleeberg, Ö. Koçak, W. A. P. Luck

      Pages 33-37

   5. Infrared Spectroscopic Study of the Strengthening of H-Bonds in Aqueous Salt Solutions

      • G. Heinje, T. Kammer, H. Kleeberg, W. A. P. Luck

      Pages 39-42

   6. Infrared Studies of Ionic Hydration in Aqueous Solutions

      • J. Lindgren, O. Kristiansson, C. Paluszkiewicz

      Pages 43-46

   7. Interactions of Cations of the Mn(II) — Zn(II) Series with Water in Solutions: Isopiestic and Spectral Results

      • Z. Libuś, J. Stangret

      Pages 47-50

   8. Raman Spectroscopic Investigations Concerning the Solvation Behaviour of Aluminium Chloride in Mixed Solvents

      • H.-H. Emons, F. Birkeneder, K. Pollmer

      Pages 51-54

   9. Dissociation Field Effect of MgS04 Ion-Pair Hydrates

      • Eberhard Neumann, Dieter Schallreuter

      Pages 55-58

   10. Hydrogen Bonding and Dehydration in Selenate Hydrates

       • H. Erfany-Far, H. Fuess

       Pages 59-62

   11. Water Molecules in Solid Hydrates — Correlation of Spectroscopic and Crystallographic Data

       • H. D. Lutz, J. Henning

       Pages 63-65

   12. Stretching Frequency Versus Bond Distance Correlation of H-Bonds in Crystalline Hydrates: The Role of the Proton Acceptors

       • W. Mikenda

       Pages 67-67

   13. Uncoupled HDO Modes Caused by Metal Guest Ions in Crystal Matrices

       • H. D. Lutz, J. Henning

       Pages 69-70

   14. Water in the Hydro-Sodalite System Na6+x(AlSiO4)6(OH)x·nH2O with O ≦ x ≦ 2 and O ≦ n ≦ 8

       • Ch. Buhl, J. Felsche, S. Luger

       Pages 71-74

   15. On the Interpretation of Isotope Effect in Mössbauer Spectroscopy

       • G. Jancsó

       Pages 75-75

   16. Isotope Effects on Nuclear Shielding as a Means of Studying Solute-Solvent Interactions

       • P. E. Hansen

       Pages 77-80

   17. Molecular Reorientations and Local Structure in Nitrate Aqueous Solutions

       • B. Rosi, M. P. Fontana

       Pages 81-87

3. Hydration of Nonionic Substances

   1. Similarities and Differences in Ionic and Nonionic Hydrates

      • H. Kleeberg

      Pages 89-112

   2. Mixed Hydrogen Bond Chains

      • P. L. Huyskens

      Pages 113-116

There is no doubt about the importance of hydration in many areas of every day life, technology, biology, medicine, science etc. During the last years many investigations have been carried out upon problems of hydration and a large amount of experimental and theoretical data has been obtained by the application of different methods. One effi­ cient possibility to stimulate progress in scientific problems is to come together and discuss existing results and ideas. This was the aim of the 35th Bunsenkolloquium and a subsequent seminar held in Marburg, FRG from April 2 -4, 1987 with respect to the "Interaction of Water in Ionic and Nonionic Hydrates". The meeting was attended by more than one hundred participants from 25 countries. It will be seen from the content of the chapters in this book, which comprises the introductory papers and more or less extended abstracts of research seminars, that it was possible not only to stress the advantages and disadvantages of each method, but also to show how information gained by one method can complement the results of another one in order to increase our overall understanding of hydration pheno­ mena. The papers are divided into sections concerning the hydration of: ions, nonionic substances, biological and macromolecular substances, surfactants as well as a section containing methods, models and theo­ ries, which may stimulate investigations on hydrations.

• influence
• infrared spectroscopy
• liquid water
• spectroscopy
• temperature
• thermodynamics

• FB Physikaliche Chemie, Universität Marburg, Marburg, Germany

  Hubertus Kleeberg

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