Electronic and Vibronic Spectra of Transition Metal Complexes II

1. Front Matter

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2. Spectroscopy of the spin sublevels of transition metal complexes

   • Tohru Azumi, Hisayuki Miki

   Pages 1-40

3. Magnetic and spectroscopic properties of Os2(O2CR)4Cl2. Evidence for a 3(δ*π*) ground state

   • Vincent M. Miskowski, Harry B. Gray

   Pages 41-57

4. Luminescence and absorption studies of transition metal ions in host crystals, pure crystals and surface environments

   • Howard H. Patterson

   Pages 59-86

5. Angular overlap model applied to transition metal complexes and dN-ions in oxide host lattices

   • Thomas Schönherr

   Pages 87-152

6. Characterization of excited electronic and vibronic states of platinum metal compounds with chelate ligands by highly frequency-resolved and time-resolved spectra

   • Hartmut Yersin, Werner Humbs, Johann Strasser

   Pages 153-249

7. Back Matter

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The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dÂ*, and ÂÂ* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy. Consequences of spin-orbit coupling, zero-field splittings, spin-lattice relaxations, chromophore-matrix interactions, Herzberg-Teller/Franck-Condon activities, and localization/delocalization properties are treated.

• Absorption
• Elektronenstruktur
• Laser
• Ligandenfeld-Theorie
• Spektroskopie
• electronic structure
• ligand field theory
• spectroscopy
• transition metal compounds
• Übergangsmetallverbindung

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