This book reviews recent advances in polymer swelling resulting from the use of novel microporous composite films. It offers a new approach to understanding sorption processes in polymer-liquid systems based on the molecular structures of the sorbed molecules and the repeat unit of the sorbent polymer. It is shown how the adsorption parameters obtained in these studies relate meaningfully with the Flory-Huggins interaction parameters. This implies that these adsorption parameters have relevance not only for swelling and drying of polymers, but also for other phenomena in which molecular sorption plays an important role, such as in chromatography and in membrane permeation.

Bibliographic Information

Book Title: Molecular Interpretations of Sorption in Polymers
Book Subtitle: Part I
Editors: Louis A. Errede
Series Title: Advances in Polymer Science
DOI: https://doi.org/10.1007/BFb0018037
Publisher: Springer Berlin, Heidelberg
eBook Packages: Springer Book Archive
Copyright Information: Springer-Verlag Berlin Heidelberg 1991
Hardcover ISBN: 978-3-540-53497-6Due: 12 August 1991
Softcover ISBN: 978-3-662-15001-6Published: 03 October 2013
eBook ISBN: 978-3-540-46323-8Published: 13 November 2005
Series ISSN: 0065-3195
Series E-ISSN: 1436-5030
Edition Number: 1
Number of Pages: VIII, 115
Topics: Polymer Sciences, Organic Chemistry, Condensed Matter Physics, Characterization and Evaluation of Materials

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Molecular Interpretations of Sorption in Polymers

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Table of contents (5 chapters)

Front Matter

Introduction

Background: Colligative-property interpretations

Sorption studies using particulate polymer enmeshed in PTFE

Correlations of α and C with other parameters

Concluding Remarks

Back Matter

Keywords

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