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Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface

  • Textbook
  • © 1983

Overview

Authors:
  1. G. A. Martynov

    1. Institute of Physical Chemistry of the USSR Academy of Sciences, Moscow, USSR

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    You can also search for this author in PubMed   Google Scholar

  2. R. R. Salem

    1. D.I. Mendeleev Chemical and Technological Institute, Moscow, USSR

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    You can also search for this author in PubMed   Google Scholar

Part of the book series: Lecture Notes in Chemistry (LNC, volume 33)

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Table of contents (10 chapters)

  1. Front Matter

    Pages N2-VI
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  2. Ionic Part of the Double Layer

    1. Introduction

      • G. A. Martynov, R. R. Salem
      Pages 1-3

    2. Classical Theories of Electrical Double Layer

      • G. A. Martynov, R. R. Salem
      Pages 4-43

    3. Physical Principles of the Statistical Theory of the Double Layer

      • G. A. Martynov, R. R. Salem
      Pages 44-56

    4. Electrostatic Adsorption in the Gouy Layer

      • G. A. Martynov, R. R. Salem
      Pages 57-64

    5. Specific Adsorption in the Stern Layer

      • G. A. Martynov, R. R. Salem
      Pages 65-97

  3. Electronic Part of the Double Layer

    1. Introduction

      • G. A. Martynov, R. R. Salem
      Pages 98-100

    2. Experimental Data

      • G. A. Martynov, R. R. Salem
      Pages 101-122

    3. Molecular Capacitor

      • G. A. Martynov, R. R. Salem
      Pages 123-129

    4. Electronic Capacitor

      • G. A. Martynov, R. R. Salem
      Pages 130-159

    5. Conclusions

      • G. A. Martynov, R. R. Salem
      Pages 160-160

  4. Back Matter

    Pages 161-176
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Keywords

About this book

Most of the properties of a metal-electrolyte interface, even the spe­ cific nature of an electrode reaction, proneness of a metal to cor­ rosion, etc., are primarily determined by the electrical double layer (EDL) at this boundary. It is therefore no surprise that for the last, at least, one hundred years intent attention should have been centered on EDL. So much of material has been gathered to date that we are easi­ ly lost in this maze of information. A substantial part of the attempts to systematize these facts is made at present within the framework of thermodynamics. Such a confined approach is undoubtedly inadequate. The Gouy-Chapman theory and the Stern-Grahame model of the dense part of EDL developed 40-70 years ago, tailored appropriately to suit the occasion, inevitably underlie any description of EDL. This route is rather too narrow to explain all the facts at our disposal. A dire necessity has thus arisen for widening the principles of the micros­ copic theory. This is precisely the objective of our monograph. Fur­ thermore, we shall dwell at length on the comparison of the theory with experiment: without such a comparative analysis, any theory, however elegant it may be, is just an empty drum.

Authors and Affiliations

  • Institute of Physical Chemistry of the USSR Academy of Sciences, Moscow, USSR

    G. A. Martynov

  • D.I. Mendeleev Chemical and Technological Institute, Moscow, USSR

    R. R. Salem

Bibliographic Information

  • Book Title: Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface

  • Authors: G. A. Martynov, R. R. Salem

  • Series Title: Lecture Notes in Chemistry

  • DOI: https://doi.org/10.1007/978-3-642-48700-2

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1983

  • Softcover ISBN: 978-3-540-11995-1Published: 01 February 1983

  • eBook ISBN: 978-3-642-48700-2Published: 06 December 2012

  • Series ISSN: 0342-4901

  • Series E-ISSN: 2192-6603

  • Edition Number: 1

  • Number of Pages: VI, 176

  • Topics: Physical Chemistry

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