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Molecular Spintronics

From Organic Semiconductors to Self-Assembled Monolayers

  • Book
  • © 2016

Overview

  • Nominated as an outstanding PhD thesis by the Unité Mixte de Physique CNRS/Thales, France
  • Includes a detailed review of the spinterface field
  • Presents the first evidence of spinterface effects at room temperature in organic spin-valves
  • Includes a detailed review of transport models through self-assembled monolayers and reports on spin-dependent transport in molecular magnetic tunnel junctions
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (8 chapters)

  1. Introduction to Organic and Molecular Spintronics

  2. Self-Assembled Monolayers for Molecular Spintronics

  3. Room Temperature Spin Injection in Organic Semiconductors

Keywords

About this book

This thesis targets molecular or organic spintronics and more particularly the spin polarization tailoring opportunities that arise from the ferromagnetic metal/molecule hybridization at interfaces: the new concept of spinterface. Molecular or organic spintronics is an emerging research field at the frontier between organic chemistry and spintronics.

The manuscript is divided into three parts, the first of which introduces the basic concepts of spintronics and advantages that molecules can bring to this field. The state of the art on organic and molecular spintronics is also presented, with a special emphasis on the physics and experimental evidence for spinterfaces.

The book’s second and third parts are dedicated to the two main experimental topics investigated in the thesis: Self-Assembled Monolayers (SAMs) and Organic Semiconductors (OSCs). The study of SAMs-based magnetic tunnel nanojunctions reveals the potential to modulate the properties of such devices “at will,”since each part of the molecule can be tuned independently like a “LEGO” building block. The study of Alq3-based spin valves reveals magnetoresistance effects at room temperature and is aimed at understanding the respective roles played by the two interfaces. Through the development of these systems, we demonstrate their potential for spintronics and provide a solid foundation for spin polarization engineering at the molecular level.

Authors and Affiliations

  • Institute of Molecular Science, University of Valencia, Paterna, Spain

    Marta Galbiati

About the author

Galbiati is a Marie Curie postdoctoral researcher at the Chemistry Institute for Molecular Science. She completed a PhD at the University of Paris Sud within the joint industrial/academic laboratory Unité Mixte de Physique CNRS/Thales under the supervision of F. Petroff, P. Seneor and R. Mattana. Her research focuses on the study of new systems with potential for the development of the areas of molecular electronics and spintronics.

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