Water and Aqueous Solutions

1. Front Matter

   Pages i-xvi

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2. Introduction and Prerequisites

   • Arieh Ben-Naim

   Pages 1-27

3. Molecular Distribution Functions

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   Pages 29-80

4. Molecular Distribution Functions and Thermodynamics

   • Arieh Ben-Naim

   Pages 81-122

5. Theory of Solutions

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   Pages 123-176

6. Generalized Molecular Distribution Functions and the Mixture-Model Approach to Liquids

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   Pages 177-221

7. Liquid Water

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   Pages 223-307

8. Water with One Simple Solute Particle

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   Pages 309-361

9. Water with Two or More Simple Solutes. Hydrophobic Interaction (HI)

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   Pages 363-439

10. Appendix

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    Pages 441-458

11. Back Matter

    Pages 459-474

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The molecular theory of water and aqueous solutions has only recently emerged as a new entity of research, although its roots may be found in age-old works. The purpose of this book is to present the molecular theory of aqueous fluids based on the framework of the general theory of liquids. The style of the book is introductory in character, but the reader is presumed to be familiar with the basic properties of water [for instance, the topics reviewed by Eisenberg and Kauzmann (1969)] and the elements of classical thermodynamics and statistical mechanics [e.g., Denbigh (1966), Hill (1960)] and to have some elementary knowledge of probability [e.g., Feller (1960), Papoulis (1965)]. No other familiarity with the molecular theory of liquids is presumed. For the convenience of the reader, we present in Chapter 1 the rudi­ ments of statistical mechanics that are required as prerequisites to an under­ standing of subsequent chapters. This chapter contains a brief and concise survey of topics which may be adopted by the reader as the fundamental "rules of the game," and from here on, the development is very slow and detailed.

• development
• research
• thermodynamics
• water
• hydrogeology

• Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel

  Arieh Ben-Naim

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