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Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers

  • Book
  • © 2003

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Editors:
  1. Ayusman Sen

    1. Department of Chemistry, The Pennsylvania State University, USA

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Part of the book series: Catalysis by Metal Complexes (CMCO, volume 27)

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Table of contents (9 chapters)

  1. Front Matter

    Pages i-x
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  2. Introduction and Future Directions

    • Ayusman Sen
    Pages 1-7

  3. Palladium-Catalysed Synthesis of Mono-Esters, -Ketones and — Aldehydes/Alcohols

    • Robert I. Pugh, Eite Drent
    Pages 9-35

  4. Production of Cooligomers from Carbon Monoxide and Ethene

    • David J. Cole-Hamilton, Ruth A. M. Robertson
    Pages 37-86

  5. Catalytic Synthesis of Copolymers and Terpolymers

    • W. P. Mul, A. W. van der Made, A. A. Smaardijk, E. Drent
    Pages 87-140

  6. Chain Transfer Mechanisms

    • Piet W. N. M. van Leeuwen
    Pages 141-188

  7. Stereochemical Aspects of Cooligomerization and Copolymerization

    • Giambattista Consiglio, Barbara Milani
    Pages 189-215

  8. Synthesis of Chiral, Optically Active Copolymers

    • Kyoko Nozaki
    Pages 217-235

  9. Chain Propagation Mechanisms

    • Ayusman Sen
    Pages 237-263

  10. Theoretical Studies on Copolymerization of Polar Monomers

    • Peter Margl, Artur Michalak, Tom Ziegler
    Pages 265-307

  11. Back Matter

    Pages 309-325
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Keywords

About this book

217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYMERIZATION OF OTHER OLEANS WITH CARBON MONOXIDE 230 5. ASYMMETRIC TERPOLYMERIZATION OF MORE THAN Two KINDS OF 232 OLEFINS WITH CARBON MONOXIDE 6. POLYKETONE CONFORMATION 233 7. CONCLUSION 234 Chapter 8. Chain Propagation Mechanisms 237 Ayusman Sen 1. INTRODUCTION 237 2. PALLADIUM (II) BASED SYSTEMS 238 3. NICKEL (II) BASED SYSTEMS 256 4. RHODIUM (I) BASED SYSTEMS 257 5. CONCLUSION 261 Chapter 9. Theoretical Studies on Copolymerization of Polar Monomers 265 Peter Margl, Artur Michalak, and Tom Ziegler 1. INTRODUCTION 265 2. COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHYLENE 267 2. 1. Experimental and calculated rates for the insertion processes for 267 copolymerization catalysed by Pd(II) systems. 2. 2. A more detailed look at the productive and unproductive cycles 270 in copolymerization catalysed by Pd(II) complexes. 2. 2. 1. The productive cycle 270 2. 2. 2. C2H4 misinsertion into an ethylene terminated polyketone 275 chain 2. 3. Experimental and calculated rates for the insertion processes for 277 alternating copolymerization catalyzed by Ni(II) systems 3. COPOLYMERIZATION OF OLEFINS WITH POLAR MONOMERS OTHER 280 THAN CO 3. 1. Preferred binding mode of oxygen containing monomers 282 3. 2. Preferred binding mode of nitrogen containing monomers 285 3. 3.

Editors and Affiliations

  • Department of Chemistry, The Pennsylvania State University, USA

    Ayusman Sen

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