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Characterization of Solutes in Nonaqueous Solvents

Proceedings of a Symposium on Spectroscopic and Electrochemical Characterization of Solute Specie

  • Conference proceedings
  • © 1978

Overview

Editors:
  1. Gleb Mamantov

    1. Department of Chemistry, University of Tennessee, Knoxville, USA

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Table of contents (15 papers)

  1. Front Matter

    Pages i-viii
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  2. Identification and Systemization of Solvent Properties Involved in the Ligand Substitution Kinetics of Labile Complexes of Nickel(II)

    • J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J. Subak Jr., K. Umemoto
    Pages 1-31

  3. Influence of the Solvent on the Orientation of Ambidentate Solvent and Ligand Molecules in the Coordination Sphere of Metal Ions

    • Floyd Farha Jr., Wayne C. Boring, Merton R. Olds, Reynold T. Iwamoto
    Pages 33-46

  4. Alkali Metal, Magnesium-25, and Silver-109 NMR Studies of Complex Compounds in Nonaqueous Solvents

    • Alexander I. Popov
    Pages 47-63

  5. Sodium-23 NMR Studies of Sodium Cation Coordination by Organic Solvents

    • Christian Detellier, Pierre Laszlo
    Pages 65-77

  6. Application of Spectroscopic and Electrochemical Techniques in Studies of Chemistry of Radical Anions and Dianions

    • M. Szwarc
    Pages 79-104

  7. Mechanisms of Nucleophilic Additions to Cation Radicals of EE Systems

    • Henry N. Blount, John F. Evans
    Pages 105-129

  8. Measurement of Conformational Rates and Equilibria by Cyclic Voltammetry

    • Dennis H. Evans, Stephen F. Nelsen
    Pages 131-154

  9. Electrochemical Synthesis and Characterization of Tetrathioethylenes in Nonaqueous Solvents

    • J. Q. Chambers, R. M. Harnden, N. D. Canfield
    Pages 155-175

  10. Thin Layer Spectroelectrochemical Studies of Cobalt and Copper Schiff Base Complexes in N,N-Dimethylformamide

    • David F. Rohrbach, Edward Deutsch, William R. Heineman
    Pages 177-195

  11. Electrochemical and Spectroscopic Studies of Rhodium and Iridium Diimine Complexes in Acetonitrile

    • Kenneth W. Hanck, M. Keith DeArmond, Gregory Kew, James L. Kahl, Horia Căldăraru
    Pages 197-221

  12. Acid-Base Dependent Redox Chemistry in Molten Chloroaluminates

    • Gleb Mamantov, Robert A. Osteryoung
    Pages 223-249

  13. Electrochemical and Spectroscopic Studies of the Chalcogens in Chloroaluminate Melts

    • Niels J. Bjerrum
    Pages 251-271

  14. Electron Free Energy Levels and Spectroscopic Character of Dilute Species in Oxidic Solvents: Relating Aqueous to Liquid (and Vitreous) Oxide Solutions

    • C. A. Angell
    Pages 273-288

  15. Recent Electroanalytical Studies in Molten Fluorides

    • D. L. Manning, Gleb Mamantov
    Pages 289-309

  16. Voltammetry of Dissolved Water and the Role of the Hydrated Electron in Fused Nitrates

    • Aida Espinola, Joseph Jordan
    Pages 311-318

  17. Back Matter

    Pages 319-325
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Keywords

About this book

This book consists of contributions by participants in the Symposium "Spectroscopic and Electrochemical Characterizat.ion of Solute Species in Non~Aqueous Solvents" which took place at the American Chemical Society Meeting, Division of Analytical Chemistry, August 31 and September I, 1976, San Francisco, California. The manuscripts were submitted to the editor during the first half of 1977 and, in most cases, represent reviews of selected research topics in the broad area of characterization of solute species in non~aqueous solvents. In organizing this Symposium, I attempted to bring together a significantly large group of research workers involved in spectro­ scopic and electrochemical studies in the three large classes of non-aqueous solvents ~ organic solvents, covalent inorganic sol­ vents and molten salts. The experimental apprcaches and problems, such as avoidance of traces of moisture and oxygen, are frequently similar for all types of non-aqueous solvents. It is hoped that this volume will be useful to all concerned with chemistry in non-aqueous solvents. Gleb l>lamantov , Contents 1. IDENTIFICATION AND SYSTEMIZATION OF SOLVENT PROPERTIES INVOLVED IN THE LIGAND SUBSTITUTION KINETICS OF LABILE COMPLEXES OF NICKEL(II) J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J.

Editors and Affiliations

  • Department of Chemistry, University of Tennessee, Knoxville, USA

    Gleb Mamantov

Bibliographic Information

  • Book Title: Characterization of Solutes in Nonaqueous Solvents

  • Book Subtitle: Proceedings of a Symposium on Spectroscopic and Electrochemical Characterization of Solute Specie

  • Editors: Gleb Mamantov

  • DOI: https://doi.org/10.1007/978-1-4613-3982-3

  • Publisher: Springer New York, NY

  • eBook Packages: Springer Book Archive

  • Copyright Information: Plenum Press, New York 1978

  • Softcover ISBN: 978-1-4613-3984-7Published: 14 October 2011

  • eBook ISBN: 978-1-4613-3982-3Published: 06 December 2012

  • Edition Number: 1

  • Number of Pages: VIII, 326

  • Topics: Analytical Chemistry, Electrochemistry, Spectroscopy/Spectrometry

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