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Homogeneous Catalysis with Metal Phosphine Complexes

  • Book
  • © 1983

Overview

Editors:
  1. Louis H. Pignolet

    1. University of Minnesota, Minneapolis, USA

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Part of the book series: Microcirculation Review (MICR)

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Table of contents (14 chapters)

  1. Front Matter

    Pages i-xvi
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  2. Historical Introduction

    • Joseph Chatt
    Pages 1-11

  3. Mechanistic Studies of Catalytic Reactions Using Spectroscopic and Kinetic Techniques

    • Chad A. Tolman, Jack W. Faller
    Pages 13-109

  4. Structurally Characterized Transition-Metal Phosphine Complexes of Relevance to Catalytic Reactions

    • Nancy L. Jones, James A. Ibers
    Pages 111-135

  5. Asymmetric Hydrogenation Reactions Using Chiral Diphosphine Complexes of Rhodium

    • John M. Brown, Penny A. Chaloner
    Pages 137-165

  6. Binuclear, Phosphine-Bridged Complexes: Progress and Prospects

    • Alan L. Balch
    Pages 167-213

  7. Hydrogenation and Hydroformylation Reactions Using Binuclear Diphosphine-Bridged Complexes of Rhodium

    • Alan R. Sanger
    Pages 215-237

  8. Functionalized Tertiary Phosphines and Related Ligands in Organometallic Coordination Chemistry and Catalysis

    • Thomas B. Rauchfuss
    Pages 239-256

  9. Polydentate Ligands and Their Effects on Catalysis

    • Devon W. Meek
    Pages 257-296

  10. Cationic Rhodium and Iridium Complexes in Catalysis

    • Robert H. Crabtree
    Pages 297-316

  11. Hydrogenation Reactions of CO and CN Functions Using Rhodium Complexes

    • Bálint Heil, László Markó, Szilárd TÅ‘rös
    Pages 317-341

  12. Decarbonylation Reactions Using Transition Metal Complexes

    • Daniel H. Doughty, Louis H. Pignolet
    Pages 343-375

  13. Homogeneous Catalysis of Oxidation Reactions Using Phosphine Complexes

    • D. Max Roundhill
    Pages 377-403

  14. Catalysis of Nitrogen-Fixing Model Studies

    • T. Adrian George
    Pages 405-441

  15. Polymer-Bound Phosphine Catalysts

    • Norman L. Holy
    Pages 443-484

  16. Back Matter

    Pages 485-489
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Keywords

About this book

The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy­ demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.

Editors and Affiliations

  • University of Minnesota, Minneapolis, USA

    Louis H. Pignolet

Bibliographic Information

  • Book Title: Homogeneous Catalysis with Metal Phosphine Complexes

  • Editors: Louis H. Pignolet

  • Series Title: Microcirculation Review

  • DOI: https://doi.org/10.1007/978-1-4613-3623-5

  • Publisher: Springer New York, NY

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer Science+Business Media New York 1983

  • Softcover ISBN: 978-1-4613-3625-9Published: 30 April 2013

  • eBook ISBN: 978-1-4613-3623-5Published: 21 November 2013

  • Edition Number: 1

  • Number of Pages: XVI, 489

  • Topics: Inorganic Chemistry

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