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Inorganic and Metal-Containing Polymeric Materials

  • Book
  • © 1990

Overview

Editors:
  1. Charles U. Pittman

    1. Mississippi State University, USA

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  2. Charles E. Carraher

    1. Florida Atlantic University, Boca Raton, USA

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  3. Martel Zeldin

    1. City University of New York, New York, USA

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  4. John E. Sheats

    1. Rider College, Lawrenceville, USA

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  5. Bill M. Culbertson

    1. Ohio State University, Columbus, USA

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Table of contents (37 chapters)

  1. Front Matter

    Pages i-1
    Download chapter PDF

  2. Inorganic and Organometallic Polymers — An Overview

    • John E. Sheats, Charles E. Carraher Jr., Charles U. Pittman Jr., Martin Zeldin, Bill M. Culbertson
    Pages 3-37

  3. Ring-Opening Polymerization (ROP) of Strained Metallocenophanes

    • John K. Pudelski, Daniel A. Foucher, Ian Manners
    Pages 39-49

  4. Cluster-Containing Metal (CO)Polymers: Production, Structure and Thermal Properties

    • N. M. Bravaya, A. D. Pomogailo, V. A. Maksakov, V. P. Kirin
    Pages 51-62

  5. Variability of Mixed-Unit Chains in Metal-Containing Polymers

    • G. I. Dzhardimalieva, A. D. Pomogailo
    Pages 63-80

  6. Metal Coordination Polymers: Eight-Coordinate Cerium(IV) and Zirconium(IV) Polymers with Varied Flexibility, Conjugation, and Stability Through Ligand Variation

    • Ronald D. Archer, Huiyong Chen, Jon A. Cronin, Sharon M. Palmer
    Pages 81-91

  7. Structural Characterization and Effects of Gibberellic Acid-Containing Organometallic Polymers as Plant Growth Regulators

    • Herbert H. Stewart, Charles E. Carraher Jr, Winn J. Soldani, Lisa Reckleben, Jose de la Torre, Shi Li Miao
    Pages 93-107

  8. The Use of Ruthenium-Containing Polythiols for Solar Energy Conversion

    • Charles E. Carraher Jr., Qingmao Zhang
    Pages 109-118

  9. Synthesis and Characterization of Aliphatic Aromatic Polyamide — Metal Complexes

    • Udai D. N. Bajpai, Sandeep Rai, Anjali Bajpai
    Pages 119-127

  10. Synthesis and Characterization of Poly(Thiooxamide) Metal Complexes

    • Anjali Bajpai, Milind Khandwe, Udai D. N. Bajpai
    Pages 129-138

  11. Multi-Electron Transfer Process of a Vanadium Dinuclear Complex for Molecular Conversions

    • Eishun Tsuchida, Kimihisa Yamamoto, Kenichi Oyaizu
    Pages 139-149

  12. Synthesis of High Molecular Weight Poly(Phenylene Sulfide) through Oxidative Polymerization with Oxygen

    • Kimihisa Yamamoto, Eishun Tsuchida
    Pages 151-160

  13. Chemical Modifications of Halomethylated Poly(Methylphenylsilane): A New and Facile Route to Functionalized Polysilanes

    • A. C. Swain, S. J. Holder, R. G. Jones, A. J. Wiseman, M. J. Went, R. E. Benfield
    Pages 161-175

  14. Siloxane Polymers with Pendant Metal Carbonyl Groups

    • Fred B. McCormick, Bradford B. Wright, Jerry W. Williams
    Pages 177-187

  15. Reaction of Trimethylsilylmethyl Substituted Silanes with Alkali Metals: Syntheses of Polycarbosilanes and Polysilanes

    • Gan Ouyang, Richard Simons, Claire Tessier
    Pages 189-197

  16. Preparation and Properties of Novel Titanosiloxane and Zirconosiloxane

    • Takahiro Gunji, Yoshimoto Abe
    Pages 199-208

  17. Synthesis of Thermosetting Preceramic Copolymer

    • O. Funayama, T. Aoki, T. Isoda
    Pages 209-218

  18. Conversion of Molecules and Clusters to Extended 3-D Cage and Channel Networks

    • Omar M. Yaghi
    Pages 219-228

  19. Poly(Phenylmetallosiloxane)S: Synthesis, Structure and Properties

    • Olga I. Shchegolikhina, Inessa V. Blagodatskikh, Yulia A. Pozdnyakova, Alexandre A. Zhdanov
    Pages 229-239

  20. Polymer-Supported Ziegler-Natta Catalysts for the Polymerization of α-Olefins and Butadiene

    • Ruicheng Ran, Charles U. Pittman Jr.
    Pages 241-253
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Keywords

About this book

Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi­ conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.

Editors and Affiliations

  • Mississippi State University, USA

    Charles U. Pittman

  • Florida Atlantic University, Boca Raton, USA

    Charles E. Carraher

  • City University of New York, New York, USA

    Martel Zeldin

  • Rider College, Lawrenceville, USA

    John E. Sheats

  • Ohio State University, Columbus, USA

    Bill M. Culbertson

Bibliographic Information

  • Book Title: Inorganic and Metal-Containing Polymeric Materials

  • Editors: Charles U. Pittman, Charles E. Carraher, Martel Zeldin, John E. Sheats, Bill M. Culbertson

  • DOI: https://doi.org/10.1007/978-1-4613-0669-6

  • Publisher: Springer New York, NY

  • eBook Packages: Springer Book Archive

  • Copyright Information: Plenum Press, New York 1990

  • Hardcover ISBN: 978-0-306-43819-6Due: 30 April 1991

  • Softcover ISBN: 978-1-4612-7919-8Published: 02 October 2011

  • eBook ISBN: 978-1-4613-0669-6Published: 06 December 2012

  • Edition Number: 1

  • Number of Pages: 432

  • Topics: Inorganic Chemistry, Organic Chemistry, Polymer Sciences, Characterization and Evaluation of Materials

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