Springer Theses

Multifunctional Molecular Magnets Based on Octacyanidometalates

Authors: Imoto, Kenta

  • Nominated by The University of Tokyo as an outstanding Ph.D. thesis
  • Demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies
  • Includes numerous step-by-step tutorials to help readers learn quickly
  • Provides a detailed description of the principle and the experimental method
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eBook $74.99
price for USA (gross)
  • ISBN 978-981-10-6135-6
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Hardcover $99.00
price for USA
  • ISBN 978-981-10-6134-9
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
About this book

This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices.

Table of contents (5 chapters)

  • Introduction

    Imoto, Kenta

    Pages 1-27

  • Observation of Light-Induced Spin-Crossover Magnetism in a Fe-[Nb(CN)8] Bimetal Assembly

    Imoto, Kenta

    Pages 29-46

  • Two-Step Spin-Crossover and Photo-Induced Spin-Crossover Ferromagnetism in Fe 2 II [NbIV(CN)8](4-Methylpyridine)8 · 2H2O

    Imoto, Kenta

    Pages 47-68

  • Observation of Coexistence of Super-Ionic Conductivity and Metamagnetism in Mn3[NbIV(CN)8]2(4-Aminopyridine)10(4-Aminopyridinium)2 · 12H2O

    Imoto, Kenta

    Pages 69-85

  • Concluding Remarks

    Imoto, Kenta

    Pages 87-88

Buy this book

eBook $74.99
price for USA (gross)
  • ISBN 978-981-10-6135-6
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Hardcover $99.00
price for USA
  • ISBN 978-981-10-6134-9
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
Multifunctional Molecular Magnets Based on Octacyanidometalates
Authors
Series Title
Springer Theses
Copyright
2017
Publisher
Springer Singapore
Copyright Holder
Springer Nature Singapore Pte Ltd.
eBook ISBN
978-981-10-6135-6
DOI
10.1007/978-981-10-6135-6
Hardcover ISBN
978-981-10-6134-9
Series ISSN
2190-5053
Edition Number
1
Number of Pages
XIII, 89
Number of Illustrations and Tables
26 b/w illustrations, 38 illustrations in colour
Topics