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Multifunctional Molecular Magnets Based on Octacyanidometalates

  • Book
  • © 2017

Overview

Authors:
  1. Kenta Imoto

    1. The University of Tokyo , Tokyo, Japan

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  • Nominated by The University of Tokyo as an outstanding Ph.D. thesis
  • Demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies
  • Includes numerous step-by-step tutorials to help readers learn quickly
  • Provides a detailed description of the principle and the experimental method
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (5 chapters)

  1. Front Matter

    Pages i-xiii
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  2. Introduction

    • Kenta Imoto
    Pages 1-27

  3. Observation of Light-Induced Spin-Crossover Magnetism in a Fe-[Nb(CN)8] Bimetal Assembly

    • Kenta Imoto
    Pages 29-46

  4. Two-Step Spin-Crossover and Photo-Induced Spin-Crossover Ferromagnetism in Fe 2 II [NbIV(CN)8](4-Methylpyridine)8 · 2H2O

    • Kenta Imoto
    Pages 47-68

  5. Observation of Coexistence of Super-Ionic Conductivity and Metamagnetism in Mn3[NbIV(CN)8]2(4-Aminopyridine)10(4-Aminopyridinium)2 · 12H2O

    • Kenta Imoto
    Pages 69-85

  6. Concluding Remarks

    • Kenta Imoto
    Pages 87-88

  7. Back Matter

    Pages 89-89
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Keywords

About this book

This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for noveloptical switching devices.


Authors and Affiliations

  • The University of Tokyo , Tokyo, Japan

    Kenta Imoto

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