Springer Theses

Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation

Authors: Matsumoto, Arimasa

  • Nominated by The University of Tokyo as an outstanding Ph.D. thesis
  • Provides examples of C-H bond activation which has attracted attention as an important chemical reaction in organic chemistry
  • Shows researchers how to develop a new reactivity of iron that is not only a simple alternative to rare metals
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eBook $69.99
price for USA (gross)
  • ISBN 978-4-431-54928-4
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Hardcover $99.00
price for USA
  • ISBN 978-4-431-54927-7
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
Softcover $99.00
price for USA
  • Customers within the U.S. and Canada please contact Customer Service at 1-800-777-4643, Latin America please contact us at +1-212-460-1500 (Weekdays 8:30am – 5:30pm ET) to place your order.
  • Due: November 10, 2016
  • ISBN 978-4-431-56248-1
  • Free shipping for individuals worldwide
About this book

Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.

Table of contents (5 chapters)

  • General Introduction

    Matsumoto, Arimasa

    Pages 1-9

  • Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent

    Matsumoto, Arimasa

    Pages 11-22

  • Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent

    Matsumoto, Arimasa

    Pages 23-64

  • Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium

    Matsumoto, Arimasa

    Pages 65-71

  • Summary and Perspectives

    Matsumoto, Arimasa

    Pages 73-74

Buy this book

eBook $69.99
price for USA (gross)
  • ISBN 978-4-431-54928-4
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Hardcover $99.00
price for USA
  • ISBN 978-4-431-54927-7
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
Softcover $99.00
price for USA
  • Customers within the U.S. and Canada please contact Customer Service at 1-800-777-4643, Latin America please contact us at +1-212-460-1500 (Weekdays 8:30am – 5:30pm ET) to place your order.
  • Due: November 10, 2016
  • ISBN 978-4-431-56248-1
  • Free shipping for individuals worldwide
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Bibliographic Information

Bibliographic Information
Book Title
Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation
Authors
Series Title
Springer Theses
Copyright
2014
Publisher
Springer Japan
Copyright Holder
Springer Japan
eBook ISBN
978-4-431-54928-4
DOI
10.1007/978-4-431-54928-4
Hardcover ISBN
978-4-431-54927-7
Softcover ISBN
978-4-431-56248-1
Series ISSN
2190-5053
Edition Number
1
Number of Pages
XIII, 74
Number of Illustrations and Tables
105 b/w illustrations
Topics