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Crystallographic Statistics in Chemical Physics

An Approach to Statistical Evaluation of Internuclear Distances in Transition Element Compounds

  • Book
  • © 1988

Overview

Authors:
  1. Fedor Valach

    1. Department of Chemical Physics and Nuclear Technique, Slovak Technical University, Bratislava, ČSSR

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  2. Jan Ondráček

    1. Institute of Chemical Technology, Computing Centre, Prague-6, ČSSR

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  3. Milan Melník

    1. Department of Inorganic Chemistry, Slovak Technical University, Bratislava, ČSSR

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Part of the book series: Inorganic Chemistry Concepts (INORGANIC, volume 12)

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Table of contents (5 chapters)

  1. Front Matter

    Pages I-X
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  2. Statistics of Interatomic Distances

    • Fedor Valach, Jan Ondráček, Milan Melník
    Pages 1-62

  3. Factors Influencing the Dispersion of Lengths of Interatomic Vectors

    • Fedor Valach, Jan Ondráček, Milan Melník
    Pages 63-85

  4. Statistics of Crystallographic Sites of Central Monatomic Entities

    • Fedor Valach, Jan Ondráček, Milan Melník
    Pages 86-124

  5. Statistics of Bond Distances Between Central Monatomic Entities and Ligands

    • Fedor Valach, Jan Ondráček, Milan Melník
    Pages 125-163

  6. Conclusions

    • Fedor Valach, Jan Ondráček, Milan Melník
    Pages 164-167

  7. Back Matter

    Pages 168-185
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Keywords

About this book

This book introduces the concept of crystallographic non- rigidity and asymmetry of the transition elements as central atoms organometallic compounds. This intrinsic behavior of central atoms in condensed matter is quantified by applying statistical approach. Averaging of extrinsic factors in crystal structures is tested by using variance analysis. Introductionof the above mentioned concept and applications of variance analysis as an approximation for considering factors influencing properties of central atomin the crystal is original and new.

Authors and Affiliations

  • Department of Chemical Physics and Nuclear Technique, Slovak Technical University, Bratislava, ČSSR

    Fedor Valach

  • Institute of Chemical Technology, Computing Centre, Prague-6, ČSSR

    Jan Ondráček

  • Department of Inorganic Chemistry, Slovak Technical University, Bratislava, ČSSR

    Milan Melník

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