Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation

Authors: Glöckner, Gottfried

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About this book

"The problems involved in separating complex macromolecules require under­ standing not only the chromatographic process but also the physicochemical behavior of the solutes." This sentence from the pen of Phyllis R. Brown 1, University of Rhode Island, can certainly be applied to synthetic copolymers whose structure is very complex indeed. Thus it may be forgiven that a book on copolymer HPLC has been written not by a trained chromatographer but by someone from the polymer side. The HPLC of synthetic polymers is often understood to mean only a synonym for size exclusion chromatography. The latter method separates polymers according to the size of the macromolecules and enables the molecular weight distribution of a sample to be evaluated. But as early as 1936, Mark and Saito attempted chromatographic fractionation of cellulose acetate on a charcoal-like adsorbent made from blood. HPLC adsorption chromatography was first applied to copolymer analysis by Teramachi et al. in 1979. Since then, another branch of polymer HPLC has arisen which has the capacity of separating copolymers by composition and enables the chemical composition distribution to be evaluated. The technique requires a suitable elution program and is mainly carried out as gradient elution.

Table of contents (12 chapters)

  • Introduction

    Glöckner, Gottfried

    Pages 1-13

  • Chemical Heterogeneity of Copolymers

    Glöckner, Gottfried

    Pages 14-24

  • Size Exclusion Liquid Chromatography of Copolymers

    Glöckner, Gottfried

    Pages 25-44

  • Special Features of Polymer HPLC

    Glöckner, Gottfried

    Pages 45-55

  • Solubility and Adsorption Effects in Polymer HPLC

    Glöckner, Gottfried

    Pages 56-74

Buy this book

eBook $99.00
price for USA (gross)
valid through November 5, 2017
  • ISBN 978-3-642-75799-0
  • Digitally watermarked, DRM-free
  • Included format: PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $129.00
price for USA
valid through November 5, 2017
  • ISBN 978-3-642-75801-0
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation
Authors
Copyright
1991
Publisher
Springer-Verlag Berlin Heidelberg
Copyright Holder
Springer-Verlag Berlin Heidelberg
eBook ISBN
978-3-642-75799-0
DOI
10.1007/978-3-642-75799-0
Softcover ISBN
978-3-642-75801-0
Edition Number
1
Number of Pages
XVI, 210
Topics