NMR Basic Principles and Progress

Chlorine, Bromine and Iodine NMR

Physico-Chemical and Biological Applications

Authors: Lindman, B., Forsen, S.

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About this book

The increasing interest in NMR spectroscopy of what in some confer­ ences in this field is commonly termed "other nuclei" is unmistakable. Chemists and biologists who employ NMR spectroscopy to study their problems have, however, been somewhat reluctant to study nuclei with electric quadrupole moments. These nuclei frequently give rise to broad NMR signals, sometimes too broad to be detectable with ordinary high resolution NMR spectrometers. Spectrometers that could cope with broad NMR signals of low intensity, "wide-line" spectrometers, have been available since the mid 1950:s but it appears that most of these instruments ended up in physical laboratories where the research was primarily directed towards solid state problems. The study of quadrupolar nuclei can provide unique and very valuable information on a variety of physico-chemical and biological systems. For one thing the relaxation of quadrupolar nuclei is in many ways easier to interpret than the relaxation of non-quadrupolar nuclei, since the former is in many cases caused by purely intramolecular interactions modulated by the molecular motion. Studies of quadrupolar relaxation have therefore furnished important information about molec­ ular reorientation and association in liquids and have played - and will certainly play for many years - an important role in testing new theoretical models of molecular motion in liquids.

Table of contents (10 chapters)

  • Introductory Aspects

    Lindman, Björn (et al.)

    Pages 1-21

  • Relaxation in Molecules or Ions With Covalently Bonded Halogens

    Lindman, Björn (et al.)

    Pages 22-59

  • Shielding Effects in Covalent Halogen Compounds

    Lindman, Björn (et al.)

    Pages 60-84

  • Scalar Spin Couplings

    Lindman, Björn (et al.)

    Pages 85-102

  • Relaxation of Chloride, Bromide and Iodide Ions

    Lindman, Björn (et al.)

    Pages 103-203

Buy this book

eBook $109.00
price for USA (gross)
  • ISBN 978-3-642-66363-5
  • Digitally watermarked, DRM-free
  • Included format: PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $149.00
price for USA
  • ISBN 978-3-642-66365-9
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
Chlorine, Bromine and Iodine NMR
Book Subtitle
Physico-Chemical and Biological Applications
Authors
Series Title
NMR Basic Principles and Progress
Series Volume
12
Copyright
1976
Publisher
Springer-Verlag Berlin Heidelberg
Copyright Holder
Springer-Verlag Berlin Heidelberg
eBook ISBN
978-3-642-66363-5
DOI
10.1007/978-3-642-66363-5
Softcover ISBN
978-3-642-66365-9
Series ISSN
0170-5989
Edition Number
1
Number of Pages
XIV, 372
Topics