Springer Theses

State-to-State Dynamical Research in the F+H2 Reaction System

Authors: Ren, Zefeng

  • Nominated as an outstanding contribution by Dalian Institute of Chemical Physics, Chinese Academy of Sciences
  • Introduces a new crossed molecular beam scattering apparatus with a high time-of-flight resolution
  • Describes the observation of Feshbach resonances in F+H2 reaction
  • Presents the measurement of nonadiabatic effects in F+D2 reaction
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eBook $74.99
price for USA (gross)
  • ISBN 978-3-642-39756-1
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
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  • Immediate eBook download after purchase
Softcover $99.00
price for USA
  • ISBN 978-3-642-39755-4
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
About this book

This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.

Table of contents (4 chapters)

  • Introduction

    Ren, Zefeng

    Pages 1-7

  • Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus

    Ren, Zefeng

    Pages 9-32

  • Dynamical Resonances in F + H2 Reactions

    Ren, Zefeng

    Pages 33-64

  • The Non-adiabatic Effects in F(2P) + D2 → DF + D

    Ren, Zefeng

    Pages 65-76

Buy this book

eBook $74.99
price for USA (gross)
  • ISBN 978-3-642-39756-1
  • Digitally watermarked, DRM-free
  • Included format: EPUB, PDF
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $99.00
price for USA
  • ISBN 978-3-642-39755-4
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
State-to-State Dynamical Research in the F+H2 Reaction System
Authors
Series Title
Springer Theses
Copyright
2014
Publisher
Springer-Verlag Berlin Heidelberg
Copyright Holder
Springer-Verlag Berlin Heidelberg
eBook ISBN
978-3-642-39756-1
DOI
10.1007/978-3-642-39756-1
Softcover ISBN
978-3-642-39755-4
Series ISSN
2190-5053
Edition Number
1
Number of Pages
XII, 77
Number of Illustrations and Tables
43 b/w illustrations, 21 illustrations in colour
Topics