Overview
- Nominated as an outstanding contribution by Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- Introduces a new crossed molecular beam scattering apparatus with a high time-of-flight resolution
- Describes the observation of Feshbach resonances in F+H2 reaction
- Presents the measurement of nonadiabatic effects in F+D2 reaction
Part of the book series: Springer Theses (Springer Theses)
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Table of contents (4 chapters)
Keywords
About this book
This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
Authors and Affiliations
Bibliographic Information
Book Title: State-to-State Dynamical Research in the F+H2 Reaction System
Authors: Zefeng Ren
Series Title: Springer Theses
DOI: https://doi.org/10.1007/978-3-642-39756-1
Publisher: Springer Berlin, Heidelberg
eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)
Copyright Information: Springer-Verlag Berlin Heidelberg 2014
Softcover ISBN: 978-3-642-39755-4Published: 22 November 2013
eBook ISBN: 978-3-642-39756-1Published: 09 November 2013
Series ISSN: 2190-5053
Series E-ISSN: 2190-5061
Edition Number: 1
Number of Pages: XII, 77
Number of Illustrations: 43 b/w illustrations, 21 illustrations in colour
Topics: Physical Chemistry, Atomic/Molecular Structure and Spectra, Theoretical and Computational Chemistry, Spectroscopy/Spectrometry