SpringerBriefs in Green Chemistry for Sustainability

MWW-Type Titanosilicate

Synthesis, Structural Modification and Catalytic Applications to Green Oxidations

Authors: Wu, P., Xu, H., Xu, L., Liu, Y., He, M.

  • Provides a complete overview of the Ti-MWW catalyst
  • Describes detailed synthesis methods for preparing Ti-MWW that differ from conventional techniques
  • Shows the special role of Ti-MWW titanosilicate in structure change, which improves its catalytic performance
  • Covers useful reactions catalyzed by Ti-MWW zeolite
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eBook $39.99
price for USA (gross)
  • ISBN 978-3-642-39115-6
  • Digitally watermarked, DRM-free
  • Included format: PDF, EPUB
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $49.99
price for USA
  • ISBN 978-3-642-39114-9
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
About this book

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.

About the authors

Peng Wu completed his BSc (1988) at Nanjing University (China) and obtained his Ph.D. (1996) from Tokyo Institute of Technology, before working as a postdoctoral fellow first at Tokyo Institute of Technology and then at Hokkaido University, Japan (1996-1999). In 1999, he moved to Yokohama National University and worked as a visiting Assistant Professor. Since 2003, he has been a full professor of physical chemistry at East China Normal University, Shanghai (China), where he holds the Cheung Kong Professorship. His research interests include design synthesis and applications of zeolites and related porous materials for environmentally friendly chemical processes. He received the Outstanding Young Researcher award from the Japan Petroleum Institute (2003) and Catalysis Society of Japan (2004), Shanghai Municipality Science and Technology Award (2007), and National Science Fund of China for Distinguished Young Scholars (2009) etc. He has published more than 150 scientific papers and holds 30 patents.

Table of contents (5 chapters)

  • Introduction

    Wu, Peng (et al.)

    Pages 1-8

  • Synthesis of Ti-MWW Zeolite

    Wu, Peng (et al.)

    Pages 9-34

  • Structural Modification of Ti-MWW: A Door to Diversity

    Wu, Peng (et al.)

    Pages 35-61

  • Catalytic Properties of Ti-MWW in Selective Oxidation Reactions

    Wu, Peng (et al.)

    Pages 63-123

  • Conclusions and Prospects

    Wu, Peng (et al.)

    Pages 125-125

Buy this book

eBook $39.99
price for USA (gross)
  • ISBN 978-3-642-39115-6
  • Digitally watermarked, DRM-free
  • Included format: PDF, EPUB
  • ebooks can be used on all reading devices
  • Immediate eBook download after purchase
Softcover $49.99
price for USA
  • ISBN 978-3-642-39114-9
  • Free shipping for individuals worldwide
  • Usually dispatched within 3 to 5 business days.
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Bibliographic Information

Bibliographic Information
Book Title
MWW-Type Titanosilicate
Book Subtitle
Synthesis, Structural Modification and Catalytic Applications to Green Oxidations
Authors
Series Title
SpringerBriefs in Green Chemistry for Sustainability
Copyright
2013
Publisher
Springer-Verlag Berlin Heidelberg
Copyright Holder
The Author(s)
eBook ISBN
978-3-642-39115-6
DOI
10.1007/978-3-642-39115-6
Softcover ISBN
978-3-642-39114-9
Series ISSN
2212-9898
Edition Number
1
Number of Pages
VIII, 125
Number of Illustrations and Tables
54 b/w illustrations, 25 illustrations in colour
Topics