Physical Chemistry

Binary Liquid Systems of Nonelectrolytes II

Heat of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions

Authors: Cibulka, I., Fontaine, J.-C., Kehiaian, H.V., Sosnkowska-Kehiaian, K.

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About this book

Vapor-liquid equilibrium data, heat of mixing (excess enthalpies), and volumetric properties of systems are required for both the applications in design of industrial technological processes and the understanding the structure and the intermolecular interactions in the systems. On the basis of classical thermodynamics the measured experimental data combined together enable us the calculation of non-measurable thermodynamic properties significant for the technological calculations. The present volume is a compilation of experimental and derived property data on subcritical binary homogeneous (single-phase) or heterogeneous (two-phase) liquid–liquid mixtures. All the components are well-defined pure substances, which are organic nonelectrolytes and water. The present volume is divided into three subvolumes (A, B, C). 800 representative data sets that cover all types of properties and chemical systems are selected for Subvolume A. While Subvolume B comprises 1032 data sets for binary mixtures containing one or two hydrocarbons, Subvolume C is providing 1014 data sets for non-hydrocarbon binary mixtures.

Table of contents (1036 chapters)

  • Introduction

    Cibulka, I. (et al.)

    Pages 1-1

  • Index of Mixtures in Subvol. IV/26B

    Cibulka, I. (et al.)

    Pages 2-42

  • Tables on Thermodynamic Properties

    Cibulka, I. (et al.)

    Pages 43-44

  • Property Groups and Property Types

    Cibulka, I. (et al.)

    Pages 45-55

  • Volumetric Properties of the Mixture Octane C8H18 + C12H26 Dodecane (VMSD1111, LB3533_V)

    Cibulka, I. (et al.)

    Pages 56-57